Wang Chi-Jen, Liu Da-Jiang, Evans James W
Department of Mathematics, National Chung Cheng University, Chiayi 62102, Taiwan.
Ames Laboratory-USDOE, Iowa State University, Ames, Iowa 50011, USA.
Phys Rev E. 2020 Feb;101(2-1):022803. doi: 10.1103/PhysRevE.101.022803.
Bistable nonequilibrium systems are realized in catalytic reaction-diffusion processes, biological transport and regulation, spatial epidemics, etc. Behavior in spatially continuous formulations, described at the mean-field level by reaction-diffusion type equations (RDEs), often mimics that of classic equilibrium van der Waals type systems. When accounting for noise, similarities include a discontinuous phase transition at some value, p_{eq}, of a control parameter, p, with metastability and hysteresis around p_{eq}. For each p, there is a unique critical droplet of the more stable phase embedded in the less stable or metastable phase which is stationary (neither shrinking nor growing), and with size diverging as p→p_{eq}. Spatially discrete analogs of these mean-field formulations, described by lattice differential equations (LDEs), are more appropriate for some applications, but have received less attention. It is recognized that LDEs can exhibit richer behavior than RDEs, specifically propagation failure for planar interphases separating distinct phases. We show that this feature, together with an orientation dependence of planar interface propagation also deriving from spatial discreteness, results in the occurrence of entire families of stationary droplets. The extent of these families increases approaching the transition and can be infinite if propagation failure is realized. In addition, there can exist a regime of generic two-phase coexistence where arbitrarily large droplets of either phase always shrink. Such rich behavior is qualitatively distinct from that for classic nucleation in equilibrium and spatially continuous nonequilibrium systems.
双稳态非平衡系统在催化反应扩散过程、生物运输与调节、空间流行病等领域中得以实现。在空间连续的表述中,由反应扩散型方程(RDEs)在平均场水平描述的行为,常常类似于经典平衡范德瓦尔斯型系统的行为。考虑噪声时,相似之处包括在某个控制参数p的特定值p_eq处出现不连续相变,在p_eq附近存在亚稳态和滞后现象。对于每个p,在较不稳定或亚稳相中存在一个嵌入的更稳定相的唯一临界液滴,它是静止的(既不收缩也不生长),并且随着p→p_eq,其尺寸发散。由晶格微分方程(LDEs)描述的这些平均场表述的空间离散类似物,对于某些应用更合适,但受到的关注较少。人们认识到,LDEs可以表现出比RDEs更丰富的行为,特别是对于分隔不同相的平面界面会出现传播失败。我们表明,这一特征以及同样源于空间离散性的平面界面传播的取向依赖性,导致出现了整个静止液滴家族。这些家族的范围在接近转变时会增加,如果实现了传播失败则可能是无限的。此外,可能存在一种一般的两相共存状态,其中任何一个相的任意大液滴总是会收缩。这种丰富的行为在定性上与平衡态和空间连续非平衡系统中的经典成核行为不同。