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关于湿地生态系统平原水库中气味特征及评价的系统研究。

A systematic study on the odorants characterization and evaluation in a plain reservoir with wetlands ecosystem.

机构信息

College of Environmental Science & Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu Province, 224051, China.

Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China; University of Chinese Academy of Sciences, Beijing, 100049, China.

出版信息

J Hazard Mater. 2020 Jul 5;393:122404. doi: 10.1016/j.jhazmat.2020.122404. Epub 2020 Feb 25.

Abstract

The odor problems in plain reservoirs are more complex compared to valley reservoirs and ground water reservoirs. Just as YL Reservoir with wetlands ecosystem in Lixiahe Plain, Jiangsu Province has been suffering from complex odors, however, the odorants were unclear. In this study, a systematic study on odorants characterization and evaluation of plain YL reservoir was accomplished. Totally musty, septic, fishy, chemical and grassy odors were first identified simultaneously, twenty-four odorants were identified correspondingly. According to odor activity value ranking, 2-methylisoborneol and geosmin, with odor activity values of 14-18 and 2.5-3.8, were major musty odorants, while bis(2-chloroisopropyl) ether, dimethyl disulfide, dimethyl trisulfide, pentanethiol and indole, with odor activity values of 15.3-18.8, 1-1.3, 1.5-2.3, 2-3 and 0.7-0.9, were major septic compounds. Fishy and grassy odors were associated with 2,4-decadienal, hexanal, nonanal, decanal, benzaldehyde and β-cyclocitral, while chemical odor was related to indane, eucalyptol, 2-nitrophenol, 2-methylphenol, tetramethylpyrazine, 1,4-dichlorobenzene, p-xylene and ethylbenzene. By reconstituting tests, 98, 95, 88, 85 and 81 % of musty, septic, fishy, chemical and grassy characteristics in source water could be explained. It was notable that wetlands ecosystem has almost no effect on odor removal. This study would offer more understandings and supports for odors's control in such source waters.

摘要

与山谷型水库和地下水库相比,平原型水库的气味问题更为复杂。就像江苏省里下河平原的具有湿地生态系统的冶陵水库一样,一直受到复杂气味的困扰,但气味成分尚不清楚。本研究对平原型冶陵水库的气味特征进行了系统的研究和评价。首次同时鉴定出霉味、腐臭味、鱼腥臭味、化学品气味和草味,相应地鉴定出 24 种气味物质。根据气味活性值排序,2-甲基异莰醇和土臭素的气味活性值分别为 14-18 和 2.5-3.8,是主要的霉味物质,而双(2-氯异丙基)醚、二甲基二硫、二甲基三硫、戊硫醇和吲哚的气味活性值分别为 15.3-18.8、1-1.3、1.5-2.3、2-3 和 0.7-0.9,是主要的腐臭味物质。鱼腥臭味和草味与 2,4-癸二烯醛、己醛、壬醛、癸醛、苯甲醛和β-环柠檬醛有关,而化学品气味与茚、桉树脑、2-硝基苯酚、2-甲基苯酚、四甲基吡嗪、1,4-二氯苯、对二甲苯和乙苯有关。通过重组试验,可以解释源水中 98%、95%、88%、85%和 81%的霉味、腐臭味、鱼腥臭味、化学品气味和草味特征。值得注意的是,湿地生态系统对气味去除几乎没有影响。本研究将为控制此类水源中的气味提供更多的认识和支持。

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