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用于合成采矿废水钴氰配合物降解的过硫酸根离子紫外光活化效率数据集。

Dataset of the efficiency of the ultraviolet light activation of persulfate ion for the degradation of cobalt cyanocomplexes in synthetic mining wastewater.

作者信息

Castilla-Acevedo Samir Fernando, Betancourt-Buitrago Luis Andrés, Dionysiou Dionysios Demetriou, Machuca-Martínez Fiderman

机构信息

Natural and Exact Sciences Department, Universidad de la Costa, Calle 58 #55 - 66, 080002, Barranquilla, Colombia.

Escuela de Ingeniería Química, Universidad del Valle, Cali, Colombia.

出版信息

Data Brief. 2020 Feb 28;29:105346. doi: 10.1016/j.dib.2020.105346. eCollection 2020 Apr.

Abstract

In recent years, the extraction of gold has become important for the development of nations. However, mining wastewater represents an environmental problem due to its high content of free cyanide-based compounds and weak and strong cyanocomplexes for the use of sodium cyanide to obtain gold from minerals. The experimental data presented show the performance of the elimination of one of the strongest cyanocomplex that can appear in mining wastewater by the ultraviolet C activation of persulfate (PS). The removal of total cobalt in solution was used as an indicator of the elimination of the cobalt cyanocomplexes that appear as transformation products from the degradation of . The data evidence that strong cyanocomplexes can be eliminated from mining wastewater. The experimental runs were divided into two parts: as a first step, the influence of the UVC light was elucidated. Afterward, five initial concentrations of persulfate ion (0.1, 0.3, 0.5, 0.7 and 0.9 g/L of PS), two pH values (11 and 13) and two additional initial concentrations of contaminant (25 mg/L and 75 mg/L of ) were examined to find the optimal parameter where the highest Co removal is obtained.

摘要

近年来,黄金开采对各国发展变得至关重要。然而,由于用于从矿石中获取黄金的氰化钠会导致采矿废水含有高含量的游离氰基化合物以及弱氰络合物和强氰络合物,采矿废水成为一个环境问题。所呈现的实验数据表明了通过过硫酸盐(PS)的紫外线C活化消除采矿废水中可能出现的最强氰络合物之一的性能。溶液中总钴的去除被用作消除作为降解转化产物出现的钴氰络合物的指标。数据证明可以从采矿废水中消除强氰络合物。实验运行分为两部分:第一步,阐明UVC光的影响。之后,研究了过硫酸根离子的五个初始浓度(0.1、0.3、0.5、0.7和0.9 g/L的PS)、两个pH值(11和13)以及污染物的另外两个初始浓度(25 mg/L和75 mg/L的 ),以找到获得最高钴去除率的最佳参数。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/56cc/7066062/a35ea6648509/gr1.jpg

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