Wang Chuang, Sun Qing, Zhao Lang, Jia Jing, Yao Lixiao, Peng Zongren
School of Electrical Engineering, Xi'an University of Technology, Xi'an 710048, China.
State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049, China.
Polymers (Basel). 2020 Mar 9;12(3):622. doi: 10.3390/polym12030622.
Laminated epoxy dielectric graded material is a commonly used insulating material with broad application prospects in power equipment. The interlaminar interfaces of laminated epoxy dielectric material between different layers form during its lamination process, and these interfaces are the crucial characteristic structures determining the mechanical and dielectric properties of laminated materials. Therefore, in order to gain a thorough understanding of physic properties behind a certain structural motif, it is necessary to study how these interfacial structures influence the mechanical and dielectric performances of graded materials. In this study, double-layered epoxy resin samples with an interlaminar interface are prepared to study their mechanical and dielectric strength. More importantly, the formation mechanism of the interface, as well as its influence on the mechanical and dielectric strength of this laminated material, is discussed. We found that a cross-linking reaction may take place between epoxy resins at the interlaminar interface, and the degree of cross-linking at the interface should be less than that in the bulk. The mechanical strength of the interlaminar interface is weaker than that of the bulk, and it is reduced by less than 40%. Moreover, the interlaminar interface is inclined to trap carriers, which improves the breakdown strength and arc ablation resistance of the laminated material. Our study of interlaminar interface properties could help in designing epoxy dielectric graded materials with better mechanical and dielectric properties.
层压环氧介质梯度材料是一种常用的绝缘材料,在电力设备中具有广阔的应用前景。层压环氧介质材料在层压过程中会形成不同层之间的层间界面,这些界面是决定层压材料机械性能和介电性能的关键特征结构。因此,为了深入了解特定结构单元背后的物理性质,有必要研究这些界面结构如何影响梯度材料的机械性能和介电性能。在本研究中,制备了具有层间界面的双层环氧树脂样品,以研究其机械强度和介电强度。更重要的是,讨论了界面的形成机制及其对这种层压材料机械强度和介电强度的影响。我们发现层间界面处的环氧树脂之间可能会发生交联反应,且界面处的交联程度应低于本体中的交联程度。层间界面的机械强度比本体弱,降低幅度小于40%。此外,层间界面易于捕获载流子,这提高了层压材料的击穿强度和耐电弧烧蚀性。我们对层间界面性能的研究有助于设计具有更好机械性能和介电性能的环氧介质梯度材料。