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利用等离子体处理的铝与水反应副产物制备γ-氧化铝

Production of Gamma Alumina Using Plasma-Treated Aluminum and Water Reaction Byproducts.

作者信息

Urbonavicius Marius, Varnagiris Sarunas, Pranevicius Liudas, Milcius Darius

机构信息

Center for Hydrogen Energy Technologies, Lithuanian Energy Institute, 3 Breslaujos, 44403 Kaunas, Lithuania.

Department of Physics, Vytautas magnus University, Vileikos g. 8-304, 44404 Kaunas, Lithuania.

出版信息

Materials (Basel). 2020 Mar 13;13(6):1300. doi: 10.3390/ma13061300.

Abstract

High purity hydrogen and solid-state byproducts are produced using a proposed plasma-activated aluminum and water reactions approach. These byproducts could be transformed into pure gamma AlO powder material, while hydrogen can be used for electricity generation. Various chemical methods can be used for the synthesis of gamma alumina, but most could result in high levels of remaining impurities. Boehmite is a cost-effective starting material for the production of high-purity AlO. Herein, we present a novel method for the synthesis of boehmite and its transformation into high-specific-surface-area γ-alumina. Specifically, this method implicates the direct reaction between distilled water and plasma-treated aluminum powder. The results show the structural and morphological changes of the byproduct of the aluminum/water reaction to boehmite and γ-AlO after a simple heating procedure (at 280 and 500 °C respectively). The high-purity hydrogen produced during the aluminum/water reaction can be used for the high-efficiency and environmentally friendly production of electrical energy.

摘要

采用一种提议的等离子体激活铝与水反应的方法来生产高纯度氢气和固态副产品。这些副产品可以转化为纯γ - AlO粉末材料,而氢气可用于发电。各种化学方法可用于合成γ - 氧化铝,但大多数方法会导致残留大量杂质。勃姆石是生产高纯度AlO的一种经济高效的起始原料。在此,我们提出了一种合成勃姆石并将其转化为高比表面积γ - 氧化铝的新方法。具体而言,该方法涉及蒸馏水与经等离子体处理的铝粉之间的直接反应。结果表明,经过简单加热程序(分别在280℃和500℃)后,铝/水反应的副产品在结构和形态上转变为勃姆石和γ - AlO。铝/水反应过程中产生的高纯度氢气可用于高效且环保的电能生产。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8465/7143390/d7239eec016b/materials-13-01300-g001.jpg

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