Liu Qingyang, Xu Juanping, Shen Liancheng, Zhou Qingjun, Su Yanjing, Qiao Lijie, Yan Yu
Beijing Advanced Innovation Center for Materials Genome Engineering, Institute for Advanced Materials and Technology, University of Science and Technology, Beijing 100083, China.
Division of Technological Sciences, Bureau of Frontier Sciences and Education, Chinese Academy of Sciences (CAS), Beijing 100864, China.
Materials (Basel). 2020 Mar 13;13(6):1304. doi: 10.3390/ma13061304.
Medium Mn steels have been considered as the next-generation materials for use in the automotive industry due to their excellent strength and ductility balance. To reduce the total weight and improve the safety of vehicles, medium Mn steels look forward to a highly promising future. However, hydrogen-induced delayed cracking is a concern for the use of high strength steels. This work is focused on the service characteristics of two kinds of medium Mn steels under different relative humidity conditions (40%, 60%, 80% and 100%). Under normal relative humidity (about 40%) at 25 °C, the hydrogen concentration in steel is 0.4 ppm. When exposed to higher relative humidity, the hydrogen concentration in steel increases slowly and reaches a stable value, about 0.8 ppm. In slow strain rate tensile tests under different relative humidity conditions, the tensile strength changed, the hydrogen concentration increased and the elongation decreased as well, thereby increasing the hydrogen embrittlement sensitivity. In other words, the smaller the tensile rate applied, the greater the hydrogen embrittlement sensitivity. In constant load tests under different relative humidity conditions, the threshold value of the delayed cracking of M7B ('M' referring to Mn, '7' meaning the content of Mn, 'B' denoting batch annealing) steel maintains a steady value of 0.82 σ (tensile strength). The threshold value of the delayed cracking of M10B significantly changed along with relative humidity. When relative humidity increased from 60% to 80%, the threshold dropped sharply from 0.63 σ to 0.52 σ. We define 80% relative humidity as the 'threshold humidity' for M10B.
中锰钢因其优异的强度和延展性平衡,被视为汽车行业的下一代材料。为了减轻车辆总重量并提高安全性,中锰钢前景广阔。然而,高强度钢的使用存在氢致延迟开裂问题。这项工作聚焦于两种中锰钢在不同相对湿度条件(40%、60%、80%和100%)下的服役特性。在25℃正常相对湿度(约40%)下,钢中的氢浓度为0.4ppm。当暴露于更高相对湿度时,钢中的氢浓度缓慢增加并达到稳定值,约为0.8ppm。在不同相对湿度条件下的慢应变速率拉伸试验中,抗拉强度发生变化,氢浓度增加,伸长率也降低,从而增加了氢脆敏感性。换句话说,施加的拉伸速率越小,氢脆敏感性越大。在不同相对湿度条件下的恒载试验中,M7B(“M”指锰,“7”表示锰含量,“B”表示分批退火)钢延迟开裂的阈值保持在0.82σ(抗拉强度)的稳定值。M10B钢延迟开裂的阈值随相对湿度显著变化。当相对湿度从60%增加到80%时,阈值从0.63σ急剧降至0.52σ。我们将80%相对湿度定义为M10B的“阈值湿度”。