• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

基于聚偏氟乙烯的复合薄膜的旋涂与微图案化优化

Spin Coating and Micro-Patterning Optimization of Composite Thin Films Based on PVDF.

作者信息

Nguyen Anh Ngoc, Solard Jeanne, Nong Huyen Thi Thanh, Ben Osman Chirine, Gomez Andres, Bockelée Valérie, Tencé-Girault Sylvie, Schoenstein Frédéric, Simón-Sorbed Maite, Carrillo Anna Esther, Mercone Silvana

机构信息

Laboratoire de Sciences des Procédés et des Matériaux (LSPM-CNRS UPR-3407), Université Sorbonne Paris Nord (USPN), 93430 Villetaneuse, France.

Institute of Materials Science, Vietnam Academy of Science and Technology, Cau Giay Distr., Hanoi, Vietnam.

出版信息

Materials (Basel). 2020 Mar 16;13(6):1342. doi: 10.3390/ma13061342.

DOI:10.3390/ma13061342
PMID:32187993
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7143455/
Abstract

We optimize the elaboration of very thin film of poly(vinylidene fluoride) (PVDF) polymer presenting a well-controlled thickness, roughness, and nano-inclusions amount. We focused our effort on the spin coating elaboration technique which is easy to transfer to an industrial process. We show that it is possible to obtain continuous and smooth thin films with mean thicknesses of 90 nm by properly adjusting the concentration and the viscosity of the PVDF solution as well as the spin rate and the substrate temperature of the elaboration process. The electro-active phase content versus the magnetic and structural properties of the composite films is reported and fully discussed. Last but not least, micro-patterning optical lithography combined with plasma etching has been used to obtain well-defined one-dimensional micro-stripes as well as squared-rings, demonstrating the easy-to-transfer silicon technology to polymer-based devices.

摘要

我们优化了聚偏氟乙烯（PVDF）聚合物超薄膜的制备工艺，使其厚度、粗糙度和纳米夹杂物含量得到良好控制。我们将精力集中在旋涂制备技术上，该技术易于转化为工业生产工艺。我们表明，通过适当调整PVDF溶液的浓度和粘度以及制备过程中的旋转速率和基板温度，可以获得平均厚度为90nm的连续且光滑的薄膜。报告并充分讨论了复合薄膜的电活性相含量与磁性和结构性能的关系。最后但同样重要的是，微图案光刻与等离子体蚀刻相结合已被用于获得轮廓清晰的一维微条纹以及方环，这证明了将硅技术轻松转移到聚合物基器件上的可行性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/d98468631c6f/materials-13-01342-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/380a8a4db37f/materials-13-01342-g0A1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/8c02717cd224/materials-13-01342-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/36e52b80b842/materials-13-01342-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/fc0262efcbee/materials-13-01342-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/08d064884fa9/materials-13-01342-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/12bbfa603af0/materials-13-01342-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/4339a381b55d/materials-13-01342-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/ef73d6110515/materials-13-01342-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/bbb68f287915/materials-13-01342-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/d98468631c6f/materials-13-01342-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/380a8a4db37f/materials-13-01342-g0A1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/8c02717cd224/materials-13-01342-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/36e52b80b842/materials-13-01342-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/fc0262efcbee/materials-13-01342-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/08d064884fa9/materials-13-01342-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/12bbfa603af0/materials-13-01342-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/4339a381b55d/materials-13-01342-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/ef73d6110515/materials-13-01342-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/bbb68f287915/materials-13-01342-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ecc8/7143455/d98468631c6f/materials-13-01342-g009.jpg

相似文献

1
Spin Coating and Micro-Patterning Optimization of Composite Thin Films Based on PVDF.基于聚偏氟乙烯的复合薄膜的旋涂与微图案化优化
Materials (Basel). 2020 Mar 16;13(6):1342. doi: 10.3390/ma13061342.
2
Piezoelectric Nanogenerators Fabricated Using Spin Coating of Poly(vinylidene fluoride) and ZnO Composite.采用聚偏氟乙烯和氧化锌复合材料旋涂法制备的压电纳米发电机
Nanomaterials (Basel). 2023 Apr 6;13(7):1289. doi: 10.3390/nano13071289.
3
Phase Inversion in PVDF Films with Enhanced Piezoresponse Through Spin-Coating and Quenching.通过旋涂和猝灭增强压电响应的聚偏氟乙烯薄膜中的相转变
Polymers (Basel). 2019 Jun 28;11(7):1096. doi: 10.3390/polym11071096.
4
Flexible, Ultrathin, and High-Efficiency Electromagnetic Shielding Properties of Poly(Vinylidene Fluoride)/Carbon Composite Films.聚偏氟乙烯/碳复合材料薄膜的柔性、超薄和高效电磁屏蔽性能。
ACS Appl Mater Interfaces. 2017 Jun 21;9(24):20873-20884. doi: 10.1021/acsami.7b04935. Epub 2017 Jun 6.
5
Chemically cross-linked thin poly(vinylidene fluoride-co-trifluoroethylene)films for nonvolatile ferroelectric polymer memory.化学交联的聚（偏二氟乙烯-共-三氟乙烯）薄膜用于非易失铁电聚合物存储器。
ACS Appl Mater Interfaces. 2011 Feb;3(2):582-9. doi: 10.1021/am1011657. Epub 2011 Feb 8.
6
Shielding Effectiveness Study of Barium Hexaferrite-Incorporated, β-Phase-Improved Poly(vinylidene fluoride) Composite Film: A Metamaterial Useful for the Reduction of Electromagnetic Pollution.掺六铁酸钡、β相改进的聚偏二氟乙烯复合薄膜的屏蔽效能研究：一种有助于减少电磁污染的超材料
ACS Appl Mater Interfaces. 2019 Jul 3;11(26):23701-23713. doi: 10.1021/acsami.9b05122. Epub 2019 Jun 20.
7
Simple synthesis of palladium nanoparticles, β-phase formation, and the control of chain and dipole orientations in palladium-doped poly(vinylidene fluoride) thin films.钯纳米粒子的简单合成、β 相形成以及钯掺杂聚（偏二氟乙烯）薄膜中链和偶极取向的控制。
Langmuir. 2012 Jul 17;28(28):10310-7. doi: 10.1021/la300983x. Epub 2012 Jul 6.
8
Fabrication of electrically bistable organic semiconducting/ferroelectric blend films by temperature controlled spin coating.通过温控旋涂法制备电双稳态有机半导体/铁电混合薄膜。
ACS Appl Mater Interfaces. 2015 Mar 25;7(11):6325-30. doi: 10.1021/acsami.5b00705. Epub 2015 Mar 12.
9
Studies of Langmuir and Langmuir-Schaefer Films of Poly(3-Hexylthiophene) and Poly(Vinylidene Fluoride).聚（3-己基噻吩）和聚偏氟乙烯的朗缪尔膜及朗缪尔-谢弗膜的研究
J Phys Chem B. 2020 Aug 13;124(32):7037-7045. doi: 10.1021/acs.jpcb.0c02990. Epub 2020 Jul 29.
10
Fabrication of flexible and self-standing inorganic-organic three phase magneto-dielectric PVDF based multiferroic nanocomposite films through a small loading of graphene oxide (GO) and Fe3O4 nanoparticles.通过少量负载氧化石墨烯（GO）和四氧化三铁（Fe3O4）纳米颗粒制备柔性自立式无机-有机三相磁电聚偏氟乙烯基多铁性纳米复合薄膜。
Dalton Trans. 2015 Sep 28;44(36):15872-81. doi: 10.1039/c5dt01509j.

引用本文的文献

1
Facile synthesis of CuONPs using juice for enhancing antibacterial activity against methicillin-resistant , beta-lactamase and tetracycline-resistant .利用果汁简便合成氧化铜纳米颗粒以增强对耐甲氧西林、β-内酰胺酶和耐四环素菌的抗菌活性。
RSC Adv. 2023 Oct 9;13(42):29363-29375. doi: 10.1039/d3ra04985j. eCollection 2023 Oct 4.
2
Piezoelectric and Magnetoelectric Effects of Flexible Magnetoelectric Heterostructure PVDF-TrFE/FeCoSiB.柔性铁电体异质结构 PVDF-TrFE/FeCoSiB 的压电和磁电效应。
Int J Mol Sci. 2022 Dec 15;23(24):15992. doi: 10.3390/ijms232415992.
3
Copper oxide nanostructured thin films processed by SILAR for optoelectronic applications.

本文引用的文献

1
Multicaloric effect in a multiferroic composite of Gd(Si,Ge) microparticles embedded into a ferroelectric PVDF matrix.嵌入铁电聚偏二氟乙烯（PVDF）基体中的钆（硅，锗）微粒多铁性复合材料中的多热效应
Sci Rep. 2019 Dec 4;9(1):18308. doi: 10.1038/s41598-019-54635-8.
2
Piezoelectric Effect and Electroactive Phase Nucleation in Self-Standing Films of Unpoled PVDF Nanocomposite Films.无极化PVDF纳米复合薄膜自支撑膜中的压电效应与电活性相形核
Nanomaterials (Basel). 2018 Sep 19;8(9):743. doi: 10.3390/nano8090743.
3
Integrated Charge Transfer in Organic Ferroelectrics for Flexible Multisensing Materials.
通过连续离子层吸附与反应法（SILAR）制备的用于光电子应用的氧化铜纳米结构薄膜。
RSC Adv. 2022 Nov 16;12(51):32853-32884. doi: 10.1039/d2ra06303d. eCollection 2022 Nov 15.
4
The Deposition of a Lectin from on the Surface of Titanium Dioxide Nanotubes Improved the Cell Adhesion, Proliferation, and Osteogenic Activity of Osteoblast-like Cells.从 在二氧化钛纳米管表面的沉积提高了成骨样细胞的细胞黏附、增殖和成骨活性。
Biomolecules. 2021 Nov 24;11(12):1748. doi: 10.3390/biom11121748.
5
Hybrid Nanocomposite Thin Films for Photovoltaic Applications: A Review.用于光伏应用的混合纳米复合薄膜：综述
Nanomaterials (Basel). 2021 Apr 26;11(5):1117. doi: 10.3390/nano11051117.
6
Nano-Modified Titanium Implant Materials: A Way Toward Improved Antibacterial Properties.纳米改性钛植入材料：通往改善抗菌性能之路
Front Bioeng Biotechnol. 2020 Nov 23;8:576969. doi: 10.3389/fbioe.2020.576969. eCollection 2020.
有机铁电体中的集成电荷转移用于柔性多功能传感材料。
Small. 2016 Sep;12(33):4502-7. doi: 10.1002/smll.201600980. Epub 2016 Jul 5.
4
Symmetry breaking in molecular ferroelectrics.分子铁电体中的对称破缺。
Chem Soc Rev. 2016 Jul 11;45(14):3811-27. doi: 10.1039/c5cs00308c.
5
Exploring Strategies for High Dielectric Constant and Low Loss Polymer Dielectrics.探索高介电常数和低损耗聚合物电介质的策略。
J Phys Chem Lett. 2014 Nov 6;5(21):3677-87. doi: 10.1021/jz501831q. Epub 2014 Oct 14.
6
The influence of hydrogen bonding on the dielectric constant and the piezoelectric energy harvesting performance of hydrated metal salt mediated PVDF films.氢键对水合金属盐介导的聚偏氟乙烯薄膜的介电常数和压电能量收集性能的影响。
Phys Chem Chem Phys. 2015 Jul 14;17(26):17429-36. doi: 10.1039/c5cp01820j.
7
Facile surface functionalization of hydrophobic magnetic nanoparticles.疏水性磁性纳米颗粒的简便表面功能化
J Am Chem Soc. 2014 Sep 10;136(36):12552-5. doi: 10.1021/ja5060324. Epub 2014 Aug 28.
8
Multiferroic polymer composites with greatly enhanced magnetoelectric effect under a low magnetic bias.具有低磁场偏置下大幅增强的磁电效应的多铁性聚合物复合材料。
Adv Mater. 2011 Sep 1;23(33):3853-8.
9
Recent progress in multiferroic magnetoelectric composites: from bulk to thin films.多铁性磁电复合材料的最新进展：从体相到薄膜。
Adv Mater. 2011 Mar 4;23(9):1062-87. doi: 10.1002/adma.201003636. Epub 2011 Feb 4.
10
Ferroelectricity and polarity control in solid-state flip-flop supramolecular rotators.固态触发器超分子转子中的铁电性和极性控制。
Nat Mater. 2009 Apr;8(4):342-7. doi: 10.1038/nmat2377. Epub 2009 Feb 8.