溶剂触发两种基于 terbium 的金属-有机骨架的结构变化及其光致发光传感。
Solvent triggering structural changes for two terbium-based metal-organic frameworks and their photoluminescence sensing.
机构信息
School of Materials and Chemical Engineering, Henan International Joint Laboratory of Rare Earth Composite Materials, Henan University of Engineering, Zhengzhou, 451191, P. R. China.
出版信息
Chem Commun (Camb). 2020 Apr 21;56(31):4320-4323. doi: 10.1039/d0cc00353k. Epub 2020 Mar 19.
PMID:32190879
Abstract
Two terbium-based metal-organic frameworks (TbPDBA-8 and TbPDBA-9) based on the same ligand have been successfully obtained. Only by changing the solvent content, TbPDBA-9 can be transformed into TbPDBA-8, and the addition of sodium formate will accelerate the process. They showed the detection performance of ascorbic acid and HO content respectively.
摘要
两种基于相同配体的铽基金属有机骨架（TbPDBA-8 和 TbPDBA-9）已被成功获得。仅仅通过改变溶剂含量，TbPDBA-9 可以转化为 TbPDBA-8，并且添加甲酸钠会加速这一过程。它们分别显示出了对抗坏血酸和 HO 含量的检测性能。
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