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[Bmmim][InSeCl]·(MIm): an organic-ligand free discrete T3 cluster for efficient hydrogen evolution under visible light irradiation.

作者信息

Wang Yanqi, Hu Qianqian, Jin Jiance, Li Jilong, Li Jianrong, Huang Xiaoying

机构信息

College of Materials Science and Engineering, Fujian Normal University, Fuzhou, Fujian 350002, People's Republic of China and State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.

出版信息

Dalton Trans. 2020 Apr 28;49(16):5020-5023. doi: 10.1039/d0dt00013b.

DOI:10.1039/d0dt00013b
PMID:32196029
Abstract

An indium selenide [Bmmim]6[In10Se16Cl4]·(MIm)2 (Bmmim = 1-butyl-2,3-dimethylimidazolium, MIm = 1-methylimidazole) cluster has been synthesized and characterized. The discrete T3 cluster could be stably dispersed in dimethyl sulfoxide, exhibiting photocatalytic hydrogen evolution activity at least six times that of the pristine in the solid state due to the exposure of more active sites.

摘要

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