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0至100°C范围内水的蒸气压公式。修订版。

Vapor Pressure Formulation for Water in Range 0 to 100 °C. A Revision.

作者信息

Wexler Arnold

机构信息

Institute for Basic Standards, National Bureau of Standards, Washington, D.C. 20234.

出版信息

J Res Natl Bur Stand A Phys Chem. 1976 Sep-Dec;80A(5-6):775-785. doi: 10.6028/jres.080A.071. Epub 1976 Oct 1.

Abstract

In 1971 Wexler and Greenspan published a formulation for the vapor pressure of water encompassing the temperature range 0 to 100 °C. In this paper a revision is made of that earlier formulation to make it consistent with the definitive experimental value of the vapor pressure of water at its triple point recently obtained by Guildner, Johnson, and Jones. The two formulations are essentially identical at temperatures from 25 to 100 °C. For temperatures below 25 °C the new formulation predicts values that are higher than the 1971 formulation. At the triple point, the vapor pressure given by the new formulation is 611.657 Pa whereas the value given by the 1971 formulation is 611.196 Pa. A table is given of the vapor pressure as a function of temperature at 0.1-deg intervals over the range 0 to 100 °C on the International Practical Temperature Scale of 1968, together with values of the temperature derivative at 1-deg intervals.

摘要

1971年,韦克斯勒和格林斯潘发表了一个涵盖0至100°C温度范围的水蒸气压公式。本文对该早期公式进行了修订,使其与吉尔德纳、约翰逊和琼斯最近获得的水在三相点的蒸气压的确定实验值相一致。这两个公式在25至100°C的温度范围内基本相同。对于低于25°C的温度,新公式预测的值高于1971年的公式。在三相点,新公式给出的蒸气压为611.657帕,而1971年公式给出的值为611.196帕。给出了一个表格,列出了在1968年国际实用温标上0至100°C范围内以0.1°C间隔的蒸气压随温度的变化情况,以及以1°C间隔的温度导数的值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d762/5312760/246f5d75479d/jresv80an5-6p775_a1bf1.jpg

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