促进1,2-金属酸盐重排的硼酸盐配合物的自由基反应。
Radical Reactions of Boron-Ate Complexes Promoting a 1,2-Metallate Rearrangement.
作者信息
Tappin Nicholas D C, Renaud Philippe
机构信息
Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern.
Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern;, Email:
出版信息
Chimia (Aarau). 2020 Feb 26;74(1-2):33-38. doi: 10.2533/chimia.2020.33.
PMID:32200784
Abstract
Recently there has been an explosion of interest in the synthetic community for the addition of radicals into unsaturated organoboron-ate complexes. This review will give a concise outline for radical processes involving boron-ate complexes which trigger a subsequent anionotropic rearrangement.
摘要
最近，合成化学领域对将自由基加成到不饱和有机硼酸酯配合物的兴趣激增。本综述将简要概述涉及硼酸酯配合物的自由基过程，这些过程会引发随后的负离子重排。
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