可见光诱导的氧化还原活性酯与二硫键的脱羧偶联反应构建 C-S 键。
Visible-light induced decarboxylative coupling of redox-active esters with disulfides to construct C-S bonds.
机构信息
Center of Cyclotron and PET Radiopharmaceuticals, Department of Nuclear Medicine and PET/CT-MRI Center, The First Affiliated Hospital of Jinan University, 613 West Huangpu Road, Tianhe District, Guangzhou 510630, China.
Center of Cyclotron and PET Radiopharmaceuticals, Department of Nuclear Medicine and PET/CT-MRI Center, The First Affiliated Hospital of Jinan University, 613 West Huangpu Road, Tianhe District, Guangzhou 510630, China and Key Laboratory of Tropical Medicinal Resources of Ministry of Education, Collaborative Innovation Center of Tropical Biological Resources, Hainan Normal University, Hainan, Haikou 571158, China.
出版信息
Chem Commun (Camb). 2020 Apr 14;56(30):4164-4167. doi: 10.1039/d0cc00451k.
A novel method has been established for the construction of C-S bonds using redox-active esters with disulfides in the presence of Ru-photoredox catalyst. This method exhibits remarkable functional group tolerance across a wide scope of substrates. Under mild conditions, a structurally diverse array of aryl alkyl sulfides is successfully and efficiently obtained through decarboxylative cross-coupling.
一种新方法已经建立，用于在 Ru-光氧化还原催化剂存在下使用带有二硫键的氧化还原活性酯构建 C-S 键。该方法在广泛的底物范围内表现出显著的官能团耐受性。在温和条件下，通过脱羧交叉偶联成功且有效地获得了结构多样的芳基烷基硫醚。
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