Li Ning, Peng Zhao-Nian, Xiong Run, Wang Ao-Cheng, Dong Zhi-Bing
School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China.
Chem Commun (Camb). 2024 Oct 15;60(83):12004-12007. doi: 10.1039/d4cc03718a.
Photoredox-catalyzed cross-coupling reaction is an efficient strategy for the construction of organic molecules. Herein, we developed a method to synthesize α-arylthioanisoles by constructing C-S bonds in the presence of a Ru-photoredox catalyst. Thus, a series of α-arylthioanisole compounds were efficiently obtained through decarboxylative cross-coupling under mild conditions. This protocol features high efficiency, broad substrate scope and good functional group tolerance.
光氧化还原催化的交叉偶联反应是构建有机分子的一种有效策略。在此，我们开发了一种在钌光氧化还原催化剂存在下通过构建C-S键来合成α-芳基硫代苯甲醚的方法。因此，在温和条件下通过脱羧交叉偶联高效地获得了一系列α-芳基硫代苯甲醚化合物。该方法具有高效、底物范围广和官能团耐受性好的特点。
