Laboratory of Isotope Ecology, Center for Nuclear Energy in Agriculture, University of São Paulo, Av. Centenário, 303, São Dimas, Piracicaba CEP 13416-000, SP, Brazil.
Ecology Department, Institute of Biological Sciences, University of Brasília, Asa Norte, Brasília CEP 70910-900, Brazil.
Molecules. 2020 Mar 24;25(6):1457. doi: 10.3390/molecules25061457.
Several previous studies on targeted food items using carbon and nitrogen stable isotope ratios in Brazil have revealed that many of the items investigated are adulterated; mislabeled or even fraud. Here, we present the first Brazilian isotopic baseline assessment that can be used not only in future forensic cases involving food authenticity, but also in human forensic anthropology studies. The δC and δN were determined in 1245 food items and 374 beverages; most of them made in Brazil. The average δC and δN of C plants were -26.7 ± 1.5‱, and 3.9 ± 3.9‱, respectively, while the average δC and δN of C plants were -11.5 ± 0.8‱ and 4.6 ± 2.6‱, respectively. The δC and δN of plant-based processed foods were -21.8 ± 4.8‱ and 3.9 ± 2.7‱, respectively. The average δC and δN of meat, including beef, poultry, pork and lamb were -16.6 ± 4.7‱, and 5.2 ± 2.6‱, respectively, while the δC and δN of animal-based processed foods were -17.9 ± 3.3‱ and 3.3 ± 3.5‱, respectively. The average δC of beverages, including beer and wine was -22.5 ± 3.1‱. We verified that C-C constitutes a large proportion of fresh meat, dairy products, as well as animal and plant-based processed foods. The reasons behind this high proportion will be addressed in this study.
先前在巴西进行的针对目标食品的碳氮稳定同位素比值的多项研究表明,许多被调查的食品都存在掺假、标签错误甚至造假的情况。在这里,我们提出了第一个巴西同位素基线评估,不仅可以用于未来涉及食品真实性的法医案例,还可以用于人类法医人类学研究。我们测定了 1245 种食品和 374 种饮料的 δC 和 δN,其中大部分是在巴西生产的。C 植物的平均 δC 和 δN 分别为-26.7 ± 1.5‰和 3.9 ± 3.9‰,而 C 植物的平均 δC 和 δN 分别为-11.5 ± 0.8‰和 4.6 ± 2.6‰。植物性加工食品的 δC 和 δN 分别为-21.8 ± 4.8‰和 3.9 ± 2.7‰。肉类(包括牛肉、禽肉、猪肉和羊肉)的平均 δC 和 δN 分别为-16.6 ± 4.7‰和 5.2 ± 2.6‰,而动物性加工食品的 δC 和 δN 分别为-17.9 ± 3.3‰和 3.3 ± 3.5‰。饮料(包括啤酒和葡萄酒)的平均 δC 为-22.5 ± 3.1‰。我们验证了 C-C 在新鲜肉类、奶制品以及动植物加工食品中占很大比例。造成这种高比例的原因将在本研究中进行探讨。