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利用台式 1H NMR 对阿甘油成分和真实性进行高通量筛选。

High-throughput screening of argan oil composition and authenticity using benchtop H NMR.

机构信息

Core Science Resources, Quadram Institute Bioscience, Norwich, UK.

Anthony Hall Group, Earlham Institute, Norwich, UK.

出版信息

Magn Reson Chem. 2020 Dec;58(12):1177-1186. doi: 10.1002/mrc.5023. Epub 2020 Apr 6.

Abstract

We use 60-MHz benchtop nuclear magnetic resonance (NMR) to acquire H spectra from argan oils of assured origin. We show that the low-field NMR spectrum of neat oil contains sufficient information to make estimates of compositional parameters and to inform on the presence of minor compounds. A screening method for quality and authenticity is presented based on nearest-neighbour outlier detection. A variety of oil types are used to challenge the method. In a survey of retail-purchased oils, several instances of fraud were found.

摘要

我们使用 60MHz 台式核磁共振(NMR)从来源有保证的阿甘油中获取 H 谱。我们表明,纯净油的低场 NMR 谱包含足够的信息,可以估算组成参数,并了解微量化合物的存在。本文提出了一种基于最近邻离群点检测的质量和真实性筛选方法。使用各种油样来检验该方法。在对零售购买的油进行调查时,发现了几起欺诈行为。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d120/8653893/9407d7857808/MRC-58-1177-g002.jpg

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