School of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing, 408100, China.
Sinochem Fuling Chongqing Chemical Industry Co., Ltd., Chongqing, 408000, China.
Environ Sci Pollut Res Int. 2020 May;27(14):17420-17424. doi: 10.1007/s11356-020-08406-y. Epub 2020 Mar 27.
The technology used in the production and exploration of shale gas creates a new source of clean energy. However, during the processes, large amounts of water-based drilling cuttings (WDC) are generated. Phosphogypsum (PG) is a by-product from the industry of phosphate fertilizer. Approximately, 5 tons of PG are generated for the production of per ton of phosphoric acid. The pile up of WDC and PG lead to severe risks of nearby soil and surface water. This paper paid attention to the recycling of WDC and PG as major raw materials in the preparation of construction cushion layer. In the research, physical properties, microstructure, and environmental pollution of the road cushion layer prepared from WDC and PG were investigated. The results show that the physical properties of compactness and unconfined compressive strength are basic meet the China national standard. The WDC cushion layer mainly constitutes of AFt, C-S-H, and plate-like Ca(OH) around the mineral phases. The leaching test revealed that the contaminants in the layer do not exceed the limits allowed by the "National Overall Discharge Standard of Sewage" (GB 8978-1996). This paper therefore outlines the effects that provide an effective way for the utilization of WDC and PG.
页岩气的生产和勘探技术创造了一种清洁能源的新来源。然而,在这个过程中,会产生大量的水基钻井废物(WDC)。磷石膏(PG)是磷肥工业的副产品。每生产一吨磷酸,大约会产生 5 吨 PG。WDC 和 PG 的堆积导致附近土壤和地表水面临严重风险。本文关注 WDC 和 PG 的回收利用,将其作为制备建筑垫层的主要原料。在研究中,对 WDC 和 PG 制备的道路垫层的物理性质、微观结构和环境污染进行了研究。结果表明,密实度和无侧限抗压强度等物理性能基本符合中国国家标准。WDC 垫层主要由 AFt、C-S-H 和板状 Ca(OH)围绕矿物相构成。浸出试验表明,该层中的污染物未超过《污水综合排放标准》(GB 8978-1996)规定的限值。因此,本文概述了其影响,为 WDC 和 PG 的利用提供了有效途径。