School of Material Science and Engineering, Chongqing Jiaotong University, Chongqing, 400074, China.
Environ Sci Pollut Res Int. 2022 Jan;29(2):2098-2106. doi: 10.1007/s11356-021-15817-y. Epub 2021 Aug 7.
Exploration and development of shale gas generate a lot of water-based drilling cuttings (WDC), which can then be used in concrete engineering. This work studied mix ratio optimization, mechanical properties, leaching characteristics and the microstructure of the WDC concrete. The results showed that the pH and COD values of these WDC were slightly above 9.0 and 60, respectively. All other indices satisfied the first grade standard of Chinese standard GB8978. On the other hand, a moderate amount of WDC can be improved concrete properties, especially its workability and compressive strength. When the water-binder ratio is 0.52 and the sand ratio is 41%, we can obtain C25 strength grade and 130 ~ 140 mm slump grade concrete by adding high efficiency water reducing agent and fly ash. XRD and SEM analysis showed that the silica and aluminum oxide in WDC reacted with calcium hydroxide to form secondary hydration products: C-S-H gel and ettringite, which are conducive to the formation of concrete strength and solidified the heavy metals and other contaminants. EDX analysis found it is known that the hydration products in WDC concrete can bind metal elements well. The environmental leaching test shows that the recycled WDC added to concrete products as aggregate and admixture is very environmentally friendly and sustainable.
页岩气的勘探和开发会产生大量水基钻井废弃物(WDC),这些废弃物可以用于混凝土工程。本工作研究了 WDC 混凝土的配合比优化、力学性能、浸出特性和微观结构。结果表明,这些 WDC 的 pH 值和 COD 值分别略高于 9.0 和 60。其他所有指标均满足中国国家标准 GB8978 一级标准。另一方面,适量的 WDC 可以改善混凝土的性能,特别是其工作性和抗压强度。当水胶比为 0.52,砂率为 41%时,通过添加高效减水剂和粉煤灰,可以获得 C25 强度等级和 130~140mm 坍落度等级的混凝土。XRD 和 SEM 分析表明,WDC 中的二氧化硅和氧化铝与氢氧化钙反应,形成二次水化产物:C-S-H 凝胶和钙矾石,这有利于混凝土强度的形成,并固化了重金属等污染物。EDX 分析表明,WDC 混凝土中的水化产物可以很好地结合金属元素。环境浸出试验表明,作为骨料和外加剂添加到混凝土制品中的回收 WDC 非常环保且可持续。