Schwen Eric M, Ramaswamy Meera, Cheng Chieh-Min, Jan Linda, Cohen Itai
Department of Physics, Cornell University, Ithaca, NY 14850, USA.
Xerox Corporation, Rochester, NY 14605, USA.
Soft Matter. 2020 Apr 15;16(15):3746-3752. doi: 10.1039/c9sm02222h.
It has recently been shown that in a broad class of disordered systems oscillatory shear training can embed memories of specific shear protocols in relevant physical parameters such as the yield strain. These shear protocols can be used to change the physical properties of the system and memories of the protocol can later be "read" out. Here we investigate shear training memories in colloidal gels, which include an attractive interaction and network structure, and discover that such systems can support memories both along and orthogonal to the training flow direction. We use oscillatory shear protocols to set and read out the yield strain memories and confocal microscopy to analyze the rearranging gel structure throughout the shear training. We find that the gel bonds remain largely isotropic in the shear-vorticity plane throughout the training process suggesting that structures formed to support shear along the training shear plane are also able to support shear along the orthogonal plane. Orthogonal memory extends the usefulness of shear memories to more applications and should apply to many other disordered systems as well.
最近的研究表明,在一大类无序系统中,振荡剪切训练可以将特定剪切协议的记忆嵌入到诸如屈服应变等相关物理参数中。这些剪切协议可用于改变系统的物理性质,并且协议的记忆随后可以被“读取”出来。在这里,我们研究了包含吸引相互作用和网络结构的胶体凝胶中的剪切训练记忆,并发现此类系统能够在与训练流动方向平行和垂直的方向上都支持记忆。我们使用振荡剪切协议来设置和读取屈服应变记忆,并使用共聚焦显微镜来分析整个剪切训练过程中凝胶结构的重排情况。我们发现,在整个训练过程中,凝胶键在剪切涡度平面内基本保持各向同性,这表明为支持沿训练剪切平面的剪切而形成的结构也能够支持沿正交平面的剪切。正交记忆将剪切记忆的实用性扩展到更多应用中,并且也应该适用于许多其他无序系统。