对《NaBH簇合物中Lewis碱性钠阴离子的实现》的评论
Comment on "Realization of Lewis Basic Sodium Anion in the NaBH Cluster".
作者信息
Pan Sudip, Frenking Gernot
机构信息
Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing, 211816, China.
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35032, Marburg, Germany.
出版信息
Angew Chem Int Ed Engl. 2020 Jun 2;59(23):8756-8759. doi: 10.1002/anie.202000229. Epub 2020 Apr 6.
PMID:32249989
Abstract
We challenge the interpretation of the chemical bond in NaBH proposed by Liu et al. We argue that NaBH has an electron-sharing Na-BH covalent bond rather than a dative bond Na →BH .
摘要
我们对刘等人提出的关于NaBH中化学键的解释提出质疑。我们认为NaBH具有电子共享的Na-BH共价键，而不是配位键Na→BH。
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