An ABC triblock copolymer based on poly(dimethylsiloxane)-poly(tert-butyl acrylate)-poly(methacrylolsobutyl POSS) is synthesized via combination of SET-LRP and ATRP from a PDMS macroinitiator. The resulting polymer can readily self-assemble into hierarchical structures through a stepwise "bottom-up" strategy, i.e. self-assembly followed by the nonsolvent vapor-induced phase separation. When a mixture of dichloromethane/dimethylformamide (DCM/DMF) is used as the casting solvent, the resulting surface (SHS) exhibits superhydrophobicity with a high water contact angle (156.7 ± 0.5°) and a low roll-off angle (<9°), and it also displays good self-cleaning property. Moreover, under the dichloromethane/methanol (DCM/MeOH) condition, a porous structure with intertwined networks of nano globules could be formed. Further infusion of the PDMS lubricant leads to the formation of a transparent slippery coating (SLIPS) with excellent water repellency, manifested by a low water contact angle hysteresis (∼3°) and a small sliding angle (∼6°). The SLIPS show excellent antifouling properties that effectively inhibit the attachment of P. aeruginosa ATCC 15692 as compared to that of the structured hydrophobic surfaces and cured PDMS surfaces.