Wang Chenghong, Guo Zhiguang
Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials, Hubei University, Wuhan 430062, P. R. China.
Nanoscale. 2020 Nov 19;12(44):22398-22424. doi: 10.1039/d0nr06009g.
Slippery liquid-infused porous surfaces inspired by the Nepenthes pitcher plant exhibit excellent performances and are known for their extremely low contact angle hysteresis (<5°) and smooth surface. In contrast, superhydrophobic surfaces (SHS) exhibit poor pressure stability, difficulty in self-healing, and difficulty in removing low surface tension liquids or organic solvents, which can affect the stable air layer. Thus, these issues can be avoided through the replacement of SHS with slippery liquid infused porous surfaces (SLIPS). In this review, the theoretical models of SHS and SLIPS are classified initially, and several design standards for the preparation of SLIPS are briefly described. Then, we focus on comparing the differences in the application of SHS and SLIPS, such as pressure stability, transparency, and droplet manipulation. However, there are still some problems that need to be improved during the preparation of SLIPS, such as the evaporation of the lubricant layer, the use of a lubricant layer of toxic perfluoropolyether and other substances, and easily lost nanostructured lubricant layer. Accordingly, several new improved methods are proposed in this review, and finally, the potential applications and development prospects of SLIPS are presented.
受猪笼草启发的注入滑液的多孔表面表现出优异的性能,以其极低的接触角滞后(<5°)和平滑表面而闻名。相比之下,超疏水表面(SHS)表现出较差的压力稳定性、自愈困难以及难以去除低表面张力液体或有机溶剂,这会影响稳定的空气层。因此,通过用注入滑液的多孔表面(SLIPS)替代超疏水表面可以避免这些问题。在本综述中,首先对超疏水表面和注入滑液的多孔表面的理论模型进行了分类,并简要描述了制备注入滑液的多孔表面的几个设计标准。然后,我们重点比较了超疏水表面和注入滑液的多孔表面在应用方面的差异,如压力稳定性、透明度和液滴操控。然而,在制备注入滑液的多孔表面的过程中仍存在一些需要改进的问题,如润滑层的蒸发、有毒全氟聚醚等物质的润滑层的使用以及易丢失的纳米结构润滑层。因此,本综述提出了几种新的改进方法,最后介绍了注入滑液的多孔表面的潜在应用和发展前景。