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一个框架中的三种隐藏才能:一种对苯二甲酸配位的铜金属有机框架,具有级联半胱氨酸氧化酶和过氧化物酶模拟活性以及用于半胱氨酸传感的刺激响应荧光。

Three hidden talents in one framework: a terephthalic acid-coordinated cupric metal-organic framework with cascade cysteine oxidase- and peroxidase-mimicking activities and stimulus-responsive fluorescence for cysteine sensing.

作者信息

Li Xin, Zhou Hao, Qi Fei, Niu Xiangheng, Xu Xuechao, Qiu Fengxian, He Yanfang, Pan Jianming, Ni Liang

机构信息

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China.

出版信息

J Mater Chem B. 2018 Oct 21;6(39):6207-6211. doi: 10.1039/c8tb02167h. Epub 2018 Sep 24.

DOI:10.1039/c8tb02167h
PMID:32254610
Abstract

A metal-organic framework (CuBDC) that possesses cascade cysteine oxidase- and peroxidase-mimicking activities and stimulus-responsive fluorescence was designed by coordinating cupric ions with terephthalic acid. The three-in-one CuBDC provided a new and extremely convenient turn-on fluorescence platform for selective and reliable detection of cysteine.

摘要

通过将铜离子与对苯二甲酸配位,设计出一种具有级联半胱氨酸氧化酶和过氧化物酶模拟活性以及刺激响应荧光的金属有机框架(CuBDC)。这种三合一的CuBDC为选择性和可靠地检测半胱氨酸提供了一个全新且极其便捷的开启式荧光平台。

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Three hidden talents in one framework: a terephthalic acid-coordinated cupric metal-organic framework with cascade cysteine oxidase- and peroxidase-mimicking activities and stimulus-responsive fluorescence for cysteine sensing.一个框架中的三种隐藏才能:一种对苯二甲酸配位的铜金属有机框架,具有级联半胱氨酸氧化酶和过氧化物酶模拟活性以及用于半胱氨酸传感的刺激响应荧光。
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2
Correction: Three hidden talents in one framework: a terephthalic acid-coordinated cupric metal-organic framework with cascade cysteine oxidase- and peroxidase-mimicking activities and stimulus-responsive fluorescence for cysteine sensing.更正:一个框架中的三项隐藏才能:一种对苯二甲酸配位的铜金属有机框架,具有级联半胱氨酸氧化酶和过氧化物酶模拟活性以及用于半胱氨酸传感的刺激响应荧光。
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