Leibniz-Institut für Katalyse e.V., Albert-Einstein-Straße 29a, 18059 Rostock, Germany.
Chem Soc Rev. 2020 May 21;49(10):3187-3210. doi: 10.1039/c9cs00615j. Epub 2020 Apr 7.
α,β-Unsaturated carbonyl compounds are key building blocks in organic chemistry. Their catalytic synthesis has received significant attention during the past decades. Among the known methodologies, carbonylation reactions represent an atom-efficient tool box to convert a variety of easily available substrates into valuable α,β-unsaturated carbonylated products including aldehydes, ketones, esters, amides, and carboxylic acids. Herein, we summarize the most important achievements in this field with a special focus on results from the last decade.
α,β-不饱和羰基化合物是有机化学中的重要构建模块。在过去的几十年中，它们的催化合成受到了广泛关注。在已知的方法中，羰基化反应是一种高效的原子工具盒，可以将各种易得的底物转化为有价值的α,β-不饱和羰基产物，包括醛、酮、酯、酰胺和羧酸。本文总结了该领域的最重要成就，特别关注了过去十年的研究成果。
