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用于透明可拉伸非对称超级电容器的具有高电化学稳定性的同轴银基金属纳米线网络

Coaxial Ag-base metal nanowire networks with high electrochemical stability for transparent and stretchable asymmetric supercapacitors.

作者信息

Park Sangbaek, Tan Alvin Wei Ming, Wang Jiangxin, Lee Pooi See

机构信息

School of Materials Science and Engineering, Nanyang Technological University Singapore, 50 Nanyang Avenue, Singapore 639798, Singapore.

出版信息

Nanoscale Horiz. 2017 Jul 1;2(4):199-204. doi: 10.1039/c7nh00024c. Epub 2017 May 2.

DOI:10.1039/c7nh00024c
PMID:32260641
Abstract

Transparent and stretchable Ag-Ni and Ag-Fe core-shell nanowire networks were fabricated as a cathode and anode, respectively, for asymmetric supercapacitors. Both electrodes showed a reversible stretchability at up to 100% strain and exhibited high electrochemical stability and specific capacitances of ∼3 mF cm with 50% optical transmittance. The asymmetric device assembled with a PVA/KOH electrolyte demonstrated a high operating voltage of 1.6 V and an excellent capacitance retention (92%) over 5000 cycles even after stretching to 35% strain.

摘要

分别制备了透明且可拉伸的Ag-Ni和Ag-Fe核壳纳米线网络,用作不对称超级电容器的阴极和阳极。两个电极在高达100%应变下均表现出可逆拉伸性,并具有高电化学稳定性和在50%透光率下约3 mF cm的比电容。用PVA/KOH电解质组装的不对称器件展示了1.6 V的高工作电压,即使在拉伸至35%应变后,在5000次循环中仍具有出色的电容保持率(92%)。

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