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基于密度泛函理论的六方密排铁在地球内核条件下的黏度

Viscosity of hcp iron at Earth's inner core conditions from density functional theory.

作者信息

Ritterbex Sebastian, Tsuchiya Taku

机构信息

Geodynamics Research Center, Ehime University, 2-5 Bunkyo-cho, Matsuyama, 790-8577, Japan.

出版信息

Sci Rep. 2020 Apr 14;10(1):6311. doi: 10.1038/s41598-020-63166-6.

Abstract

The inner core, extending to 1,221 km above the Earth's center at pressures between 329 and 364 GPa, is primarily composed of solid iron. Its rheological properties influence both the Earth's rotation and deformation of the inner core which is a potential source of the observed seismic anisotropy. However, the rheology of the inner core is poorly understood. We propose a mineral physics approach based on the density functional theory to infer the viscosity of hexagonal close packed (hcp) iron at the inner core pressure (P) and temperature (T). As plastic deformation is rate-limited by atomic diffusion under the extreme conditions of the Earth's center, we quantify self-diffusion in iron non-empirically. The results are applied to model steady-state creep of hcp iron. Here, we show that dislocation creep is a key mechanism driving deformation of hcp iron at inner core conditions. The associated viscosity agrees well with the estimates from geophysical observations supporting that the inner core is significantly less viscous than the Earth's mantle. Such low viscosity rules out inner core translation, with melting on one side and solidification on the opposite, but allows for the occurrence of the seismically observed fluctuations in inner core differential rotation.

摘要

内核延伸至距离地球中心1221千米深处,压力在329至364吉帕之间,主要由固态铁组成。其流变特性既影响地球自转,也影响内核变形,而内核变形是观测到的地震各向异性的一个潜在来源。然而,人们对内核的流变学了解甚少。我们提出一种基于密度泛函理论的矿物物理学方法,以推断六方密排(hcp)铁在核内压力(P)和温度(T)下的粘度。由于在地球中心的极端条件下,塑性变形受原子扩散的速率限制,我们非经验性地量化了铁中的自扩散。结果被应用于模拟hcp铁的稳态蠕变。在此,我们表明位错蠕变是驱动hcp铁在核内条件下变形的关键机制。相关粘度与地球物理观测的估计结果吻合良好,这支持了内核的粘性明显低于地球地幔的观点。如此低的粘度排除了内核一侧熔化而另一侧凝固的内核平移情况,但允许出现地震观测到的内核差动旋转波动。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c863/7156496/540cc18676b6/41598_2020_63166_Fig1_HTML.jpg

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