Centre for Environmental Sustainability and Water Security (IPASA), Research Institute of Sustainable Environment (RISE), School of Civil Engineering, Faculty of Engineering, Universiti Teknologi Malaysia (UTM), 81310, Skudai, Malaysia.
Department of Earth Sciences, Resources and Environmental Engineering, School of Creative Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, 169-8555, Tokyo, Japan.
Sci Rep. 2020 Apr 14;10(1):6412. doi: 10.1038/s41598-020-63575-7.
This paper aims to examine the effect of cellulose nanocrystals (CNCs) derived from oil palm empty fruit bunch fiber (EFB) incorporating cement mortar on its structural performances. Cellulose nanocrystals (CNCs) were extracted from α-cellulose extracted from EFB using an acid hydrolysis process with a concentration of acid used was 64% w/v under the temperature of 45 °C for 60 minutes. The Cellulose nanocrystals (CNCs) were mixed into the cement mortar ranging from 0 to 0.8% w/w and its mechanical properties were determined. The developed CNCs mortar was characterized for their compressive and flexural properties as well as microstructure. The influence of CNCs concentration, curing method, dispersion of CNCs on mortar's mechanical performance was thoroughly examined to find out the optimum condition. Overall results revealed that an addition of 0.4% cellulose nanocrystals has shown to increase the compressive and flexural strength to 46% and 20%, respectively cured under the wrapping method. The hydration of cementitious composites also improved significantly with the addition of CNCs by the formation of highly crystalline of portlandite observed under the XRD test. This present work demonstrates the importance of palm oil empty fruit bunch waste as a sustainable resource of cellulose nanocrystals admixture to achieve structural strength of cement mortar and promotes green technologies in construction.
本文旨在研究源自油棕果串纤维(EFB)的纤维素纳米晶体(CNC)掺入水泥砂浆对其结构性能的影响。使用酸水解工艺从 EFB 中的α-纤维素中提取纤维素纳米晶体(CNC),酸的浓度为 64% w/v,温度为 45°C,时间为 60 分钟。将纤维素纳米晶体(CNC)混入水泥砂浆中,浓度范围为 0 至 0.8% w/w,并测定其力学性能。对开发的 CNCs 砂浆进行抗压和抗弯性能以及微观结构的特性研究。彻底研究了 CNCs 浓度、养护方法、CNCs 在砂浆中的分散性对砂浆力学性能的影响,以找出最佳条件。总体结果表明,在包裹法养护下,添加 0.4%的纤维素纳米晶体可使抗压强度和抗弯强度分别提高 46%和 20%。添加 CNCs 还可显著改善胶凝复合材料的水化作用,通过 XRD 测试观察到氢氧化钙的高结晶度形成。本工作证明了棕榈油果串废料作为纤维素纳米晶体掺合料的可持续资源的重要性,可实现水泥砂浆的结构强度,并促进建筑领域的绿色技术发展。