• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

铜（0）介导的甲基丙烯酸甲酯单电子转移活性自由基聚合：功能化石墨烯作为自由基引发剂的便捷工具

Copper (0) Mediated Single Electron Transfer-Living Radical Polymerization of Methyl Methacrylate: Functionalized Graphene as a Convenient Tool for Radical Initiator.

作者信息

Murali Adhigan, Sampath Srinivasan, Appukutti Achuthan Boopathi, Sakar Mohan, Chandrasekaran Suryanarayanan, Suthanthira Vanitha N, Joseph Bensingh R, Abdul Kader M, Jaisankar Sellamuthu N

机构信息

School for Advanced Research in Polymers (SARP)-Advanced Research School for Technology and Product Simulation (ARSTPS), Central Institute of Plastics Engineering & Technology (CIPET), Ministry of Chemicals & Fertilizers, Govt. of India, Chennai 600032, India.

Department of Materials Science, School of Technology, Central University of Tamil Nadu, Thiruvarur 610101, India.

出版信息

Polymers (Basel). 2020 Apr 10;12(4):874. doi: 10.3390/polym12040874.

DOI:10.3390/polym12040874
PMID:32290159
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7240427/
Abstract

Polymer nanocomposites have been synthesized by the covalent addition of bromide-functionalized graphene (Graphene-Br) through the single electron transfer-living radical polymerization technique (SET-LRP). Graphite functionalized with bromide for the first time via an efficient route using mild reagents has been designed to develop a graphene based radical initiator. The efficiency of sacrificial initiator (ethyl α-bromoisobutyrate) has also been compared with a graphene based initiator towards monitoring their Cu(0) mediated controlled molecular weight and morphological structures through mass spectroscopy (MOLDI-TOF) and field emission scanning electron microscopy (FE-SEM) analysis, respectively. The enhancement in thermal stability is observed for graphene-grafted-poly(methyl methacrylate) (G--PMMA) at 392 °C, which may be due to the influence ofthe covalent addition of graphene, whereas the sacrificial initiator used to synthesize G--PMMA (S) has low thermal stability as analyzed by TGA. A significant difference is noticed on their glass transition and melting temperatures by DSC. The controlled formation and structural features of the polymer-functionalized-graphene is characterized by Raman, FT-IR, UV-Vis spectroscopy, NMR, and zeta potential measurements. The wettability measurements of the novel G--PMMA on leather surface were found to be better in hydrophobic nature with a water contact angle of 109 ± 1°.

摘要

通过单电子转移活性自由基聚合技术（SET-LRP），通过溴化物官能化石墨烯（Graphene-Br）的共价加成合成了聚合物纳米复合材料。首次通过使用温和试剂的有效途径用溴化物官能化的石墨被设计用于开发基于石墨烯的自由基引发剂。还比较了牺牲引发剂（α-溴代异丁酸乙酯）与基于石墨烯的引发剂的效率，分别通过质谱（MOLDI-TOF）和场发射扫描电子显微镜（FE-SEM）分析来监测它们的Cu(0)介导的可控分子量和形态结构。在392°C下观察到石墨烯接枝聚甲基丙烯酸甲酯（G-PMMA）的热稳定性增强，这可能是由于石墨烯共价加成的影响，而通过热重分析（TGA）分析，用于合成G-PMMA（S）的牺牲引发剂具有较低的热稳定性。通过差示扫描量热法（DSC）发现它们的玻璃化转变温度和熔点有显著差异。通过拉曼光谱、傅里叶变换红外光谱（FT-IR）、紫外可见光谱、核磁共振（NMR）和zeta电位测量对聚合物官能化石墨烯的可控形成和结构特征进行了表征。发现新型G-PMMA在皮革表面的润湿性测量结果具有更好的疏水性，水接触角为109±1°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/727d0c24bc57/polymers-12-00874-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/ebefb34027c4/polymers-12-00874-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/1e2707153705/polymers-12-00874-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/b1865432faa0/polymers-12-00874-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/4d2df954940a/polymers-12-00874-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/afae2a90b2f2/polymers-12-00874-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/5d7ffb43539a/polymers-12-00874-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/727d0c24bc57/polymers-12-00874-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/ebefb34027c4/polymers-12-00874-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/1e2707153705/polymers-12-00874-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/b1865432faa0/polymers-12-00874-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/4d2df954940a/polymers-12-00874-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/afae2a90b2f2/polymers-12-00874-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/5d7ffb43539a/polymers-12-00874-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7934/7240427/727d0c24bc57/polymers-12-00874-g007.jpg

相似文献

1
Copper (0) Mediated Single Electron Transfer-Living Radical Polymerization of Methyl Methacrylate: Functionalized Graphene as a Convenient Tool for Radical Initiator.铜（0）介导的甲基丙烯酸甲酯单电子转移活性自由基聚合：功能化石墨烯作为自由基引发剂的便捷工具
Polymers (Basel). 2020 Apr 10;12(4):874. doi: 10.3390/polym12040874.
2
Controlled atom transfer radical polymerization of MMA onto the surface of high-density functionalized graphene oxide.高密度功能化氧化石墨烯表面 MMA 的可控原子转移自由基聚合。
Nanoscale Res Lett. 2014 Jul 10;9(1):345. doi: 10.1186/1556-276X-9-345. eCollection 2014.
3
Comparative Study of Polymer-Grafted BaTiO Nanoparticles Synthesized Using Normal ATRP as Well as ATRP and ARGET-ATRP with Sacrificial Initiator with a Focus on Controlling the Polymer Graft Density and Molecular Weight.采用常规原子转移自由基聚合（ATRP）以及带有牺牲引发剂的 ATRP 和ARGET-ATRP 对比研究接枝聚合物的 BaTiO3 纳米粒子，重点在于控制聚合物接枝密度和分子量。
Molecules. 2023 May 30;28(11):4444. doi: 10.3390/molecules28114444.
4
Synthesis and Characterization of ABA-Type Triblock Copolymers Using Novel Bifunctional PS, PMMA, and PCL Macroinitiators Bearing -xylene-bis(2-mercaptoethyloxy) Core.使用含对二甲苯双（2-巯基乙氧基）核的新型双官能聚苯乙烯、聚甲基丙烯酸甲酯和聚己内酯大分子引发剂合成及表征ABA型三嵌段共聚物。
Polymers (Basel). 2023 Sep 18;15(18):3813. doi: 10.3390/polym15183813.
5
Grafting Poly(Methyl Methacrylate) (PMMA) from Cork via Atom Transfer Radical Polymerization (ATRP) towards Higher Quality of Three-Dimensional (3D) Printed PMMA/Cork--PMMA Materials.通过原子转移自由基聚合（ATRP）在软木上接枝聚甲基丙烯酸甲酯（PMMA）以提高三维（3D）打印的PMMA/软木-PMMA材料的质量
Polymers (Basel). 2020 Aug 19;12(9):1867. doi: 10.3390/polym12091867.
6
Preparation of poly(methyl methacrylate) grafted titanate nanotubes by in situ atom transfer radical polymerization.通过原位原子转移自由基聚合制备聚甲基丙烯酸甲酯接枝钛酸纳米管
Nanotechnology. 2008 Dec 10;19(49):495604. doi: 10.1088/0957-4484/19/49/495604. Epub 2008 Nov 19.
7
Click synthesis of quaternized poly(dimethylaminoethyl methacrylate) functionalized graphene oxide with improved antibacterial and antifouling ability.点击合成具有增强抗菌和防污能力的季铵化聚（甲基丙烯酸二甲氨基乙酯）功能化氧化石墨烯
Colloids Surf B Biointerfaces. 2016 May 1;141:196-205. doi: 10.1016/j.colsurfb.2016.01.046. Epub 2016 Jan 29.
8
Effect of Graphene Oxide on the Reaction Kinetics of Methyl Methacrylate In Situ Radical Polymerization via the Bulk or Solution Technique.氧化石墨烯对通过本体或溶液技术进行的甲基丙烯酸甲酯原位自由基聚合反应动力学的影响。
Polymers (Basel). 2017 Sep 8;9(9):432. doi: 10.3390/polym9090432.
9
Preparation of poly(methyl methacrylate) grafted hydroxyapatite nanoparticles via reverse ATRP.通过反向原子转移自由基聚合制备聚（甲基丙烯酸甲酯）接枝羟基磷灰石纳米粒子。
J Colloid Interface Sci. 2011 Aug 15;360(2):415-21. doi: 10.1016/j.jcis.2011.04.093. Epub 2011 May 4.
10
Surface-initiated atom transfer radical polymerization of methyl methacrylate from magnetite nanoparticles at ambient temperature.室温下在磁铁矿纳米颗粒上进行甲基丙烯酸甲酯的表面引发原子转移自由基聚合反应。
J Nanosci Nanotechnol. 2006 Jul;6(7):2018-24. doi: 10.1166/jnn.2006.343.

引用本文的文献

1
Antibiofilm Effects of Modifying Polyvinylidene Fluoride Membranes with Polyethylenimine, Poly(acrylic acid) and Graphene Oxide.用聚乙烯亚胺、聚丙烯酸和氧化石墨烯改性聚偏氟乙烯膜的抗生物膜效果
Polymers (Basel). 2024 Dec 5;16(23):3418. doi: 10.3390/polym16233418.
2
Unveiling the potential of emergent nanoscale composite polymer electrolytes for safe and efficient all solid-state lithium-ion batteries.揭示新型纳米复合聚合物电解质在安全高效全固态锂离子电池中的潜力。
RSC Adv. 2024 Sep 25;14(42):30618-30629. doi: 10.1039/d4ra05134c. eCollection 2024 Sep 24.
3
Polymethyl Methacrylate-Based Bone Cements Containing Carbon Nanotubes and Graphene Oxide: An Overview of Physical, Mechanical, and Biological Properties.

本文引用的文献

1
Preparation and characterization of polyurethane-carbon nanotube composites.聚氨酯-碳纳米管复合材料的制备与表征
Soft Matter. 2005 Oct 21;1(5):386-394. doi: 10.1039/b509038e.
2
Persian waxing of graphite: towards green large-scale production of graphene.石墨的波斯蜡处理：迈向绿色大规模生产石墨烯
Chem Commun (Camb). 2019 May 10;55(37):5331-5334. doi: 10.1039/c9cc01822k. Epub 2019 Apr 4.
3
Contact angle measurement of free-standing square-millimeter single-layer graphene.独立式正方形毫米单层石墨烯的接触角测量。
含碳纳米管和氧化石墨烯的聚甲基丙烯酸甲酯基骨水泥：物理、力学和生物学性能概述
Polymers (Basel). 2020 Jun 30;12(7):1469. doi: 10.3390/polym12071469.
Nat Commun. 2018 Oct 10;9(1):4185. doi: 10.1038/s41467-018-06608-0.
4
Protection from Below: Stabilizing Hydrogenated Graphene Using Graphene Underlayers.从底部保护：使用石墨烯底层稳定氢化石墨烯。
Langmuir. 2017 Dec 5;33(48):13749-13756. doi: 10.1021/acs.langmuir.7b03596. Epub 2017 Nov 17.
5
Carbon Nanotube Reinforced Polymer-Stabilized Liquid Crystal Device: Lowered and Thermally Invariant Threshold with Accelerated Dynamics.碳纳米管增强聚合物稳定液晶器件：降低和热不变阈值与加速动力学。
ACS Appl Mater Interfaces. 2017 Aug 9;9(31):26622-26629. doi: 10.1021/acsami.7b08825. Epub 2017 Jul 26.
6
A Highly Sensitive Immunosorbent Assay Based on Biotinylated Graphene Oxide and the Quartz Crystal Microbalance.基于生物素化氧化石墨烯和石英晶体微天平的高灵敏度免疫吸附测定法。
ACS Appl Mater Interfaces. 2016 Jan 27;8(3):1893-902. doi: 10.1021/acsami.5b10026. Epub 2016 Jan 12.
7
Formation mechanism and optimization of highly luminescent N-doped graphene quantum dots.高度发光的 N 掺杂石墨烯量子点的形成机制与优化。
Sci Rep. 2014 Jun 18;4:5294. doi: 10.1038/srep05294.
8
Ordered supramolecular gels based on graphene oxide and tetracationic cyclophanes.基于氧化石墨烯和四阳离子环芳烃的有序超分子凝胶。
Adv Mater. 2014 May;26(17):2725-9, 2617. doi: 10.1002/adma.201304334. Epub 2014 Feb 12.
9
Wettability of graphene.石墨烯的润湿性。
Nano Lett. 2013 Apr 10;13(4):1509-15. doi: 10.1021/nl304647t. Epub 2013 Mar 7.
10
Surface-initiated polymerization from carbon nanotubes: strategies and perspectives.碳纳米管引发的表面聚合：策略与展望。
Chem Soc Rev. 2013 Jan 21;42(2):677-704. doi: 10.1039/c2cs35226e.