Ge Fangqing, Fei Liang, Zhang Jinju, Wang Chaoxia
College of Textile Science and Engineering, Key Laboratory of Eco-Textile, Ministry of Education, Jiangnan University, Wuxi 214122, People's Republic of China.
ACS Appl Mater Interfaces. 2020 May 13;12(19):21854-21862. doi: 10.1021/acsami.0c03194. Epub 2020 Apr 30.
A sensitive electro-thermochromic Janus fabric driven by voltage is demonstrated via a facial double side coating. The graphene forms a conductive layer that allows Joule heating to supply the thermal resource for the electro-thermochromic behavior of polyester fabric. The thermochromic dye with reversible color-changing property is coated on the opposite side of the graphene layer. The color of electro-thermochromic Janus fabric changes from blue to white with a gradual heating that exceeded 45 °C at the applied voltage of 10 V. The switching rate of color is rapid with the increase of temperature from the room temperature to above 45 °C in 8 s, resulting from the superior resistive heating of the graphene. The electrical conductivity of the electro-thermochromic Janus fabric is not disturbed once undergoing a bending angle range from 30° to 150° and the temperature remains stable after 1000 bending cycles which clearly indicates the excellent flexibility of the fabric. The steady signal in the heating/cooling curve is observed after 500 cycles, pointing out the outstanding durability of the electro-thermochromic Janus fabric under the supplied voltage. It is realizable that the color of electro-thermochromic Janus fabric is triggered accurately by varying the supplied voltage. The simplicity of this design makes it attractive for the application of flexible electro-thermochromic textile, such as active visual camouflage, personal thermal management, and information displays.
通过表面双面涂层展示了一种由电压驱动的灵敏电热致变色双面织物。石墨烯形成导电层,可通过焦耳热为聚酯织物的电热致变色行为提供热资源。具有可逆变色特性的热致变色染料涂覆在石墨烯层的另一侧。在10 V的施加电压下,随着温度逐渐升高超过45°C,电热致变色双面织物的颜色从蓝色变为白色。由于石墨烯优异的电阻加热性能,在8秒内从室温升高到45°C以上时,颜色切换速率很快。电热致变色双面织物在30°至150°的弯曲角度范围内电导率不受影响,并且在1000次弯曲循环后温度保持稳定,这清楚地表明了织物具有出色的柔韧性。在500次循环后观察到加热/冷却曲线中的稳定信号,表明电热致变色双面织物在施加电压下具有出色的耐久性。通过改变施加电压可以精确触发电热致变色双面织物的颜色。这种设计的简单性使其在柔性电热致变色纺织品的应用中具有吸引力,如主动视觉伪装、个人热管理和信息显示。