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通过在石墨烯/水性聚氨酯复合材料中浸涂制造的导电对位芳纶针织物的电加热性能

Electrical Heating Performance of Electro-Conductive Para-aramid Knit Manufactured by Dip-Coating in a Graphene/Waterborne Polyurethane Composite.

作者信息

Kim Hyelim, Lee Sunhee, Kim Hanseong

机构信息

Research Institute of Convergence Design, Dong-A University, Busan, 49315, Republic of Korea.

Dept. Organic Material Science and Engineering, Pusan National University, Busan, 46241, Republic of Korea.

出版信息

Sci Rep. 2019 Feb 6;9(1):1511. doi: 10.1038/s41598-018-37455-0.

Abstract

An electro-conductive para-aramid knit was manufactured by a dip-coating in a graphene/waterborne polyurethane(WPU) composite for confirming to use as a fabric heating element applicable to a protective clothing requiring durability. The para-aramid knit was dipped in 8 wt% graphene/WPU composite solution up to five-coat cycles. As a result of electro-conductive textile by number of dip-coating cycles, the electrical, and specifically electrical heating performances were increased number of cycles from one to five. The sample with the best electrical and electrical heating performance was the five-coat sample, and to improve those properties it was hot-pressed at 100 °C, 120 °C, 140 °C and 160 °C. After hot pressing, the entire surface of the sample was filled with graphene/WPU composite and indicated smoothly surface, thus the electrical and electrical heating performance was improved than the five-coat sample. The best performance of was indicated hot-pressed at 140 °C, with a surface resistivity and capacitance of 7.5 × 10 Ω/sq and 89.4 pF, respectively. When a voltage of 50 V was applied, the surface temperature reached 54.8 °C. The five-coat sample with hot-pressed at 140 °C could be applied to a heat-resistant para-aramid knit glove with the touch screen of a mobile phone and electric heating performance.

摘要

通过在石墨烯/水性聚氨酯(WPU)复合材料中进行浸涂来制造一种导电对位芳纶针织品,以确认其可用作适用于需要耐用性的防护服的织物加热元件。将对位芳纶针织品浸入8 wt%的石墨烯/WPU复合溶液中,进行多达五次的涂层循环。作为浸涂循环次数对导电纺织品的影响结果,随着循环次数从1次增加到5次,其电学性能,特别是电加热性能得到了提高。具有最佳电学和电加热性能的样品是五涂层样品,为了改善这些性能,在100°C、120°C、140°C和160°C下对其进行热压。热压后,样品的整个表面都充满了石墨烯/WPU复合材料,表面光滑,因此其电学和电加热性能比五涂层样品有所提高。在140°C下热压显示出最佳性能,表面电阻率和电容分别为7.5×10Ω/sq和89.4 pF。当施加50 V电压时,表面温度达到54.8°C。在140°C下热压的五涂层样品可应用于具有手机触摸屏和电加热性能的耐热对位芳纶针织手套。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/67b9/6365530/719809300125/41598_2018_37455_Fig1_HTML.jpg

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