Dziuba Thomas, Luo Yuansu, Samwer Konrad
I. Physikalisches Institut, Georg-August-University Göttingen, D-370077 Göttingen, Germany.
J Phys Condens Matter. 2020 May 22;32(34). doi: 10.1088/1361-648X/ab8aa2.
Recently, ultrastable glasses gained growing attention due to the revelation of the mechanism leading towards the understanding of glasses and glass transition in general. We report the adaptation of vapor deposition techniques to create ultrastable amorphous phases of CuZrwith different mechanical properties. Investigations using atomic force acoustic microscopy reveal a connection between an enhanced elastic modulus, its low potential energy and its homogeneity throughout the sample. Here, higher stability is always accompanied by high homogeneity. We relate the preparation conditions to the resulting mechanical properties, potentially opening a path to systematically engineer ultrastability in metallic glasses. Furthermore, we give a qualitative explanation for our results in the framework of the potential energy landscape, providing insights to the origin of ultrastability in metallic glasses in general.
最近,超稳定玻璃受到了越来越多的关注,这是因为揭示了通向理解玻璃及一般玻璃转变的机制。我们报道了采用气相沉积技术来制备具有不同机械性能的超稳定非晶态CuZr相。利用原子力声学显微镜进行的研究揭示了弹性模量增强、低势能及其在整个样品中的均匀性之间的联系。在此,更高的稳定性总是伴随着高均匀性。我们将制备条件与所得的机械性能相关联,这可能为系统地设计金属玻璃的超稳定性开辟一条途径。此外,我们在势能景观的框架内对我们的结果给出了定性解释,为一般金属玻璃中超稳定性的起源提供了见解。