Zhang Aitang, Liu Rui, Tian Jinmi, Huang Weiguo, Liu Jingquan
College of Materials Science and Engineering, Institute for Graphene Applied Technology Innovation, Collaborative Innovation Centre for Marine Biomass Fibers, Materials and Textiles of Shandong Provincev, Qingdao University, Qingdao, 266071, P. R. China.
Chemistry. 2020 May 20;26(29):6342-6359. doi: 10.1002/chem.202000191. Epub 2020 Apr 28.
Novel nanomaterials and advanced nanotechnology continuously push forward the rapid development of sustainable energy conversion and storage equipment. An emerging family of two-dimensional transition-metal carbides, nitrides and carbonitrides, also known as MXenes, have attracted increasing attention and in depth investigation. Benefitting from their unique intrinsic properties, MXenes have attracted significant attention and they have been considered as promising candidate materials for the development of environmentally friendly energy resources. A large number of studies show that MXenes have great potential in energy conversion and storage fields. Despite of their exceptional properties, MXenes also have some inherent characteristics, such as low capacities and unstable retention performances, which severely hinder their prospect applications in energy conversion and storage fields. In this Minireview, the latest progress on MXenes and their hybrid composites with small molecules, polymers, carbon or metal ions, and their applications in energy conversion and storage fields is highlighted, including their use in different types of batteries, supercapacitors, hydrogen/oxygen evolution reactions, electromagnetic interference absorption/shielding and solar steam generation. In addition, the critical challenges and further development prospects of MXene-based materials are also introduced.
新型纳米材料和先进纳米技术不断推动可持续能源转换与存储设备的快速发展。一类新兴的二维过渡金属碳化物、氮化物和碳氮化物,也被称为MXenes,已引起越来越多的关注并得到深入研究。得益于其独特的固有特性,MXenes已备受关注,并被视为开发环境友好型能源的有前景的候选材料。大量研究表明,MXenes在能量转换和存储领域具有巨大潜力。尽管MXenes具有优异的性能,但它们也有一些固有特性,如低容量和不稳定的保持性能,这严重阻碍了它们在能量转换和存储领域的应用前景。在这篇综述中,重点介绍了MXenes及其与小分子、聚合物、碳或金属离子的杂化复合材料的最新进展,以及它们在能量转换和存储领域的应用,包括它们在不同类型电池、超级电容器、析氢/析氧反应、电磁干扰吸收/屏蔽和太阳能蒸汽产生中的应用。此外,还介绍了基于MXene的材料面临的关键挑战和进一步的发展前景。