Zeng Jin-Yue, Wang Xiao-Shuang, Zhang Xian-Zheng
Key Laboratory of Biomedical Polymers of Ministry of Education and Department of Chemistry, Wuhan University, Wuhan, 430072, P.R. China.
The Institute for Advanced Studies, Wuhan University, Wuhan, 430072, P.R. China.
Chemistry. 2020 Dec 15;26(70):16568-16581. doi: 10.1002/chem.202001105. Epub 2020 Sep 23.
Covalent organic frameworks (COFs) are an emerging kind of crystalline porous polymers that present the precise integration of organic building blocks into extensible structures with regular pores and periodic skeletons. The diversity of organic units and covalent linkages makes COFs a rising materials platform for the design of structure and functionality. Herein, recent research progress in developing COFs for photoluminescent materials is summarised. Structural and functional design strategies are highlighted and fundamental problems that need to be solved are identified, in conjunction with potential applications from perspectives of photoluminescent materials.
共价有机框架（COFs）是一种新兴的结晶多孔聚合物，它将有机结构单元精确整合到具有规则孔道和周期性骨架的可扩展结构中。有机单元和共价键的多样性使COFs成为一个用于结构和功能设计的新兴材料平台。本文总结了开发用于光致发光材料的COFs的最新研究进展。重点介绍了结构和功能设计策略，确定了需要解决的基本问题，并从光致发光材料的角度探讨了其潜在应用。
