Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan.
Chem Commun (Camb). 2020 May 28;56(43):5835-5838. doi: 10.1039/d0cc02628j. Epub 2020 Apr 24.
A hexagonal cobalt(ii) metallacycle and its "lipid packaged" derivatives, [Co(R-bisterpy)]X (R = H, OCH, OCH; X = BF, C-Glu), have been synthesized and characterized. The compounds incorporating BF anions formed sphere-like aggregates while the compounds with C-Glu lipid anions gave double-layered honeycomb architectures composed of hexagonal stacked tubular structures, which exhibit spin crossover behaviour.
已合成并表征了一种六方钴(ii)金属环及其“脂质包裹”衍生物[Co(R-bisterpy)]X（R = H，OCH，OCH；X = BF，C-Glu）。含有 BF 阴离子的化合物形成球状聚集体，而含有 C-Glu 脂质阴离子的化合物则形成由六边形堆叠管状结构组成的双层蜂窝状结构，其表现出自旋交叉行为。
