Akiyoshi Ryohei, Kuroiwa Keita, Alao Amolegbe Saliu, Nakaya Manabu, Ohtani Ryo, Nakamura Masaaki, Lindoy Leonard F, Hayami Shinya
Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan.
Chem Commun (Camb). 2017 Apr 25;53(34):4685-4687. doi: 10.1039/c7cc01501a.
Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type Co(C-terpy) (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours.
两亲性阴离子与Co(C-terpy)型（n = 15 - 20）长链烷基化阳离子钴（II）配合物之间形成的自组装杂化超分子结构已被合成，并通过透射电子显微镜（TEM）、粉末X射线衍射（PXRD）和磁化率测量进行了表征。这些杂化物呈现出线状或卷曲片状的超分子排列，且与奇数和偶数烷基链有关，其中钴（II）中心表现出逐渐的自旋交叉行为。
