路易斯酸催化的羰基-烯烃复分解反应
Lewis acid-catalyzed carbonyl-olefin metathesis.
作者信息
Riehl Paul S, Schindler Corinna S
机构信息
University of Michigan, Department of Chemistry, Willard Henry Dow Laboratory, 930 North University Ave., Ann Arbor, MI 48109, US.
出版信息
Trends Chem. 2019 May;1(2):272-273. doi: 10.1016/j.trechm.2019.02.011. Epub 2019 Mar 15.
Abstract
Catalytic carbonyl-olefin metathesis reactions enable direct carbon-carbon bond formation between carbonyl and olefin substrates relying on carbonyl-activation with a suitable Lewis acid. Based on this reaction design principle, efficient protocols for intermolecular carbonyl-olefin metathesis, as well as ring-closing and ring-opening carbonyl-olefin metathesis have been developed.
摘要
催化羰基-烯烃复分解反应能够使羰基和烯烃底物之间直接形成碳-碳键，这依赖于用合适的路易斯酸对羰基进行活化。基于此反应设计原理，已开发出用于分子间羰基-烯烃复分解以及关环和开环羰基-烯烃复分解的有效方法。
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