Ludwig Jacob R, Schindler Corinna S
Willard Henry Dow Laboratory, Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
Synlett. 2017;28(13):1501-1509. doi: 10.1055/s-0036-1588827.
Olefin-olefin metathesis has led to important advances in diverse fields of research, including synthetic chemistry, materials science and chemical biology. The corresponding carbonyl-olefin metathesis also enables direct carbon-carbon bond formation from readily available precursors, however, currently available synthetic procedures are significantly less advanced. This Synpacts article provides an overview of recent achievements in the field of Lewis acid-mediated and Lewis-acid catalyzed carbonyl-olefin metathesis reactions.
烯烃复分解反应在包括合成化学、材料科学和化学生物学在内的多个研究领域都取得了重要进展。相应的羰基-烯烃复分解反应也能够从易得的前体直接形成碳-碳键，然而，目前可用的合成方法仍不够先进。这篇Synpacts文章概述了路易斯酸介导和路易斯酸催化的羰基-烯烃复分解反应领域的最新成果。
