利用低功率可见激光二极管雕刻系统制备还原氧化石墨烯柔性电极的新方法。

New fabrication method for producing reduced graphene oxide flexible electrodes by using a low-power visible laser diode engraving system.

作者信息

Chuquitarqui A, Cotet L C, Baia M, György E, Magyari K, Barbu-Tudoran L, Baia L, Díaz-González M, Fernández-Sánchez C, Pérez Del Pino A

机构信息

Instituto de Ciencia de Materiales de Barcelona, Consejo Superior de Investigaciones Científicas (ICMAB-CSIC), Campus UAB 08193, Bellaterra, Spain.

出版信息

Nanotechnology. 2020 Aug 7;31(32):325402. doi: 10.1088/1361-6528/ab8d67. Epub 2020 Apr 27.

Abstract

The fabrication of bendable electronic devices is a scientific-technological area of very rapid advance in which new materials and fabrication techniques are being continuously developed. In these kinds of devices, the fabrication of flexible conductive electrodes adherent to the substrate is a key factor. Further, eco-friendliness, low cost and fast production are essential requirements for the successful progress of new technologies. In this work, a novel method for obtaining graphene-based flexible electrodes is presented. Conductive films were obtained by means of the visible laser irradiation of graphene oxide layers deposited on polyethylene terephthalate substrates and self-standing membranes sandwiched between glass slides. Despite the low power of the laser system, the numerical simulations indicate the development of temperatures over 1000 K throughout the irradiated material. The laser-induced spatially confined heating leads to the reduction of the graphene oxide material, whereas the glass-based sandwich assembly avoids reoxidation from the surrounding air. By scanning and pixelated modes, reduced graphene oxide electrodes, up to 100 μm in thickness, and with a resistivity as low as 6 × 10 Ωm, were obtained in an easy and versatile way. Proof-of-concept microsupercapacitors and electrochemical sensors were fabricated with this technique, showing promising performance.

摘要

可弯曲电子设备的制造是一个快速发展的科技领域,新材料和制造技术不断涌现。在这类设备中,制备与基底附着的柔性导电电极是一个关键因素。此外,生态友好、低成本和快速生产是新技术成功发展的基本要求。在这项工作中,提出了一种制备基于石墨烯的柔性电极的新方法。通过对沉积在聚对苯二甲酸乙二酯基底上的氧化石墨烯层以及夹在载玻片之间的自支撑膜进行可见光激光辐照,获得了导电薄膜。尽管激光系统功率较低,但数值模拟表明,整个被辐照材料的温度会升至1000 K以上。激光诱导的空间受限加热导致氧化石墨烯材料还原,而基于玻璃的夹层组件可避免被周围空气再氧化。通过扫描和像素化模式,以简便通用的方式获得了厚度达100μm、电阻率低至6×10Ωm的还原氧化石墨烯电极。利用该技术制造了概念验证微型超级电容器和电化学传感器,显示出良好的性能。

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