Coppola Bartolomeo, Di Maio Luciano, Incarnato Loredana, Tulliani Jean-Marc
Department of Applied Science and Technology (DISAT), Politecnico di Torino, INSTM R.U. Lince Laboratory, Corso Duca Degli Abruzzi 24, 10129 Torino, Italy.
Department of Industrial Engineering (DIIN), University of Salerno, Via Giovanni Paolo II 132, 84084 Fisciano (SA), Italy.
Nanomaterials (Basel). 2020 Apr 24;10(4):814. doi: 10.3390/nano10040814.
Polypropylene/carbon nanotubes (PP/CNTs) nanocomposites with different CNTs concentrations (i.e., 1, 2, 3, 5 and 7 wt%) were prepared and tested as strain gauges for structures monitoring. Such sensors were embedded in cementitious mortar prisms and tested in 3-point bending mode recording impedance variation at increasing load. First, thermal (differential scanning calorimetry (DSC), thermo-gravimetric analysis (TGA)), mechanical (tensile tests) and morphological (FE-SEM) properties of nanocomposites blends were assessed. Then, strain-sensing tests were carried out on PP/CNTs strips embedded in cementitious mortars. PP/CNTs nanocomposites blends with CNTs content of 1, 2 and 3 wt% did not show significant results because these concentrations are below the electrical percolation threshold (EPT). On the contrary, PP/CNTs nanocomposites with 5 and 7 wt% of CNTs showed interesting sensing properties. In particular, the best result was highlighted for the PP/CNT nanocomposite with 5 wt% CNTs for which an average gauge factor (GF) of approx. 1400 was measured. Moreover, load-unload cycles reported a good recovery of the initial impedance. Finally, a comparison with some literature results, in terms of GF, was done demonstrating the benefits deriving from the use of PP/CNTs strips as strain-gauges instead of using conductive fillers in the bulk matrix.
制备了具有不同碳纳米管(CNT)浓度(即1、2、3、5和7重量%)的聚丙烯/碳纳米管(PP/CNT)纳米复合材料,并将其作为用于结构监测的应变片进行测试。此类传感器被嵌入水泥砂浆棱柱体中,并在三点弯曲模式下进行测试,记录加载过程中的阻抗变化。首先,评估了纳米复合材料共混物的热性能(差示扫描量热法(DSC)、热重分析(TGA))、力学性能(拉伸试验)和形态学性能(场发射扫描电子显微镜(FE-SEM))。然后,对嵌入水泥砂浆中的PP/CNT条带进行了应变传感测试。碳纳米管含量为1、2和3重量%的PP/CNT纳米复合材料共混物未显示出显著结果,因为这些浓度低于导电渗流阈值(EPT)。相反,碳纳米管含量为5和7重量%的PP/CNT纳米复合材料显示出有趣的传感性能。特别是,碳纳米管含量为5重量%的PP/CNT纳米复合材料表现出最佳结果,其平均应变片系数(GF)约为1400。此外,加载-卸载循环显示初始阻抗具有良好的恢复性。最后,在应变片系数方面与一些文献结果进行了比较,证明了使用PP/CNT条带作为应变片而非在基体中使用导电填料的益处。