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原位热还原氧化石墨烯/环氧树脂复合材料:热性能和力学性能

In situ thermally reduced graphene oxide/epoxy composites: thermal and mechanical properties.

作者信息

Olowojoba Ganiu B, Eslava Salvador, Gutierrez Eduardo S, Kinloch Anthony J, Mattevi Cecilia, Rocha Victoria G, Taylor Ambrose C

机构信息

1Mechanics of Materials Division, Department of Mechanical Engineering, Imperial College London, London, UK.

2Centre for Advanced Structural Ceramics, Department of Materials, Imperial College London, London, UK.

出版信息

Appl Nanosci. 2016;6(7):1015-1022. doi: 10.1007/s13204-016-0518-y. Epub 2016 Jan 30.

Abstract

Graphene has excellent mechanical, thermal, optical and electrical properties and this has made it a prime target for use as a filler material in the development of multifunctional polymeric composites. However, several challenges need to be overcome to take full advantage of the aforementioned properties of graphene. These include achieving good dispersion and interfacial properties between the graphene filler and the polymeric matrix. In the present work, we report the thermal and mechanical properties of reduced graphene oxide/epoxy composites prepared via a facile, scalable and commercially viable method. Electron micrographs of the composites demonstrate that the reduced graphene oxide (rGO) is well dispersed throughout the composite. Although no improvements in glass transition temperature, tensile strength and thermal stability in air of the composites were observed, good improvements in thermal conductivity (about 36 %), tensile and storage moduli (more than 13 %) were recorded with the addition of 2 wt% of rGO.

摘要

石墨烯具有优异的机械、热、光学和电学性能,这使其成为开发多功能聚合物复合材料时用作填充材料的主要目标。然而,要充分利用石墨烯的上述性能,还需要克服几个挑战。这些挑战包括在石墨烯填料与聚合物基体之间实现良好的分散性和界面性能。在本工作中,我们报道了通过一种简便、可扩展且具有商业可行性的方法制备的还原氧化石墨烯/环氧树脂复合材料的热性能和机械性能。复合材料的电子显微镜照片表明,还原氧化石墨烯(rGO)在整个复合材料中分散良好。尽管未观察到复合材料的玻璃化转变温度、拉伸强度和在空气中的热稳定性有所提高,但添加2 wt%的rGO后,热导率(约36%)、拉伸模量和储能模量(超过13%)有了显著提高。

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