Preparation and characterization of highly transparent hydrophobic nanocellulose film using corn husks as main material.

In this paper, nanocellulose was extracted from agricultural waste corn husks. Transparent hydrophobic membranes containing silica were fabricated through two facile methods including surface coating and internal grafting. The results showed that: the nanocellulose prepared by TEMPO-mediated oxidation and high pressure homogenization not only retained the type and crystal structure of the original cellulose, but also increased the crystallinity to 64.5% and improved the thermal stability. Both surface coating and internal grafting methods had successfully loaded silica onto films. The internal grafting film had a silica content of 10.5%, which was mainly present inside the film. The light transmittance of this film was 84.4% and the surface contact angle to water was 152.6°. The content of silica on the surface coating film was 5.7%, and they were mainly distributed on the surface of the film to form a nano-scale rough surface. The light transmittance of the surface coating film was 87.8% and the surface contact angle to water was 165.7°. Compared to the film prepared by internal grafting method, the nanocellulose film prepared by surface coating method contained less nano silica and had better properties including higher transparency, higher surface roughness and excellent hydrophobic anti-fouling properties.