磷烯及其 P-手性衍生物的简明合成。
Concise Synthesis of Phospholene and Its P-Stereogenic Derivatives.
机构信息
College of Chemistry, Green Catalysis Center, International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, P. R. China.
出版信息
J Org Chem. 2020 Nov 20;85(22):14772-14778. doi: 10.1021/acs.joc.0c00545. Epub 2020 May 19.
PMID:32375482
Abstract
A simple method to build phospholene derivatives has been achieved in a one-pot reaction with readily available -alkynylaryl bromides and alkylphosphine oxides. This method is also applicable to synthesize P-stereogenic phospholenes, and the resulting chiral phosphine was utilized as a ligand for coordination chemistry.
摘要
一种简单的方法已经实现了在一锅反应中构建膦烯衍生物，使用易得的 -炔基芳基溴化物和烷基氧化膦。这种方法也适用于合成 P 手性膦烯，所得手性膦作为配体用于配位化学。
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