College of Chemistry, Green Catalysis Center, International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, P. R. China.
J Org Chem. 2020 Nov 20;85(22):14772-14778. doi: 10.1021/acs.joc.0c00545. Epub 2020 May 19.
A simple method to build phospholene derivatives has been achieved in a one-pot reaction with readily available -alkynylaryl bromides and alkylphosphine oxides. This method is also applicable to synthesize P-stereogenic phospholenes, and the resulting chiral phosphine was utilized as a ligand for coordination chemistry.
一种简单的方法已经实现了在一锅反应中构建膦烯衍生物，使用易得的 -炔基芳基溴化物和烷基氧化膦。这种方法也适用于合成 P 手性膦烯，所得手性膦作为配体用于配位化学。
