新型罕见的 clerodane 二萜过氧化物来自埃及高山茶（Qourtom）及其作为草药疗法和植物营养素制剂的化学系统。
New Rare -Clerodane Diterpene Peroxides from Egyptian Mountain Tea (Qourtom) and Its Chemosystem as Herbal Remedies and Phytonutrients Agents.
机构信息
Pharmacognosy Department, Faculty of Pharmacy, Deraya University, El-Minia 61519, Egypt.
Chemistry Department, Faculty of Science, Minia University, El-Minia 61519, Egypt.
出版信息
Molecules. 2020 May 6;25(9):2172. doi: 10.3390/molecules25092172.
Genus , the largest genera of the family Lamiaceae, and its species are frequently used as herbal teas due to their essential oils. Tubers of some species are also consumed as important nutrients for humans and animals due to their carbohydrate contents. Three new -clerodane diterpene peroxides, named stachaegyptin F-H ( and ), together with two known compounds, stachysperoxide () and stachaegyptin A (), were isolated from aerial parts. Their structures were determined using a combination of spectroscopic techniques, including HR-FAB-MS and extensive 1D and 2D NMR (H, C NMR, DEPT, H-H COSY, HMQC, HMBC and NOESY) analyses. Additionally, a biosynthetic pathway for the isolated compounds (-) was discussed. The chemotaxonomic significance of the isolated diterpenoids of in comparison to the previous reported ones from other species was also studied.
穗花香薷属是唇形科中最大的属，由于其精油的存在，其物种常被用作草药茶。由于碳水化合物的含量，一些穗花香薷属的块茎也被人类和动物作为重要的营养物质来食用。从穗花香薷属的地上部分分离得到了三个新的 -裂环二萜过氧化物，分别命名为stachaegyptin F-H（和），以及两个已知化合物 stachysperoxide（）和 stachaegyptin A（）。通过 HR-FAB-MS 和广泛的 1D 和 2D NMR（H、C NMR、DEPT、H-H COSY、HMQC、HMBC 和 NOESY）分析等光谱技术确定了它们的结构。此外，还讨论了分离化合物 (-) 的生物合成途径。还研究了与其他穗花香薷属物种以前报道的化合物相比，穗花香薷属分离出的二萜的化学分类学意义。
Zotero 插件