University of Applied Forest Sciences Rottenburg, Schadenweilerhof, 72108 Rottenburg, Germany.
University of Applied Forest Sciences Rottenburg, Schadenweilerhof, 72108 Rottenburg, Germany.
Waste Manag. 2020 May 15;109:136-148. doi: 10.1016/j.wasman.2020.04.047. Epub 2020 May 11.
The purpose of this study is to test alternative additives for trace element (TE) supplementation and process stabilization during anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW) and sewage sludge. Process instabilities due to acidification are a typical problem in waste fermentation. Provision with minerals and TE is crucial for microorganisms in AD to work effectively, allowing higher organic loading rates within the digester without risking acid accumulation. In batch-fermentation tests, different mixture configurations of OFMSW, digested sewage sludge and biomass ashes were evaluated. Based on an extensive characterization of the TE contained in wood ashes, suitable combinations of digested sewage sludge and OFMSW as a baseline substrate together with ash additives were derived. While high dosages of ash reduced biogas production, 1:1 mix of ash and OFMSW facilitated higher CH yields (6%). The supplementation of ashes increased the pH-value within AD and CO precipitation through metal oxides in situ elevated the CH concentration in biogas up to 98%. Therefore, ashes may increase the efficiency of AD and serve as a basis for a new gas purification method, minimizing technical effort. Additional investigations are needed to examine long-term effects as well as financial and legal aspects such as possible ways of digestate usage. As a further area of research, the transferability of batch-test results into practical applications is identified.
本研究旨在测试痕量元素(TE)补充的替代添加剂,并在有机固体废物(OFMSW)和污水污泥的厌氧消化(AD)过程中稳定化。由于酸化导致的过程不稳定是废物发酵中的一个典型问题。在 AD 中,矿物质和 TE 的供应对微生物至关重要,使微生物能够在消化器中有效运作,在不增加酸积累风险的情况下提高有机负荷率。在分批发酵试验中,评估了 OFMSW、消化污水污泥和生物质灰分的不同混合物配置。基于对木灰中所含 TE 的广泛表征,得出了合适的消化污水污泥和 OFMSW 组合作为基线底物,以及灰分添加剂。虽然高剂量的灰分减少了沼气产量,但 1:1 的灰分和 OFMSW 混合物促进了更高的 CH 产率(6%)。灰分的添加提高了 AD 中的 pH 值,并且通过原位金属氧化物沉淀 CO 提高了沼气中 CH 浓度至 98%。因此,灰分可以提高 AD 的效率,并作为一种新的气体净化方法的基础,从而最小化技术投入。需要进一步的研究来检验长期效果以及财务和法律方面,例如可能的消化物使用方式。作为进一步的研究领域,确定将批处理测试结果转化为实际应用的可转移性。