Xue Yudong, Wang Yunting
College of Engineering, Korea University, Seoul 136-701, Republic of Korea.
School of Chemical and Environmental Engineering, China University of Mining and Technology of Beijing, Beijing 100083, P. R. China.
Nanoscale. 2020 May 28;12(20):10912-10932. doi: 10.1039/d0nr02705g.
α-Fe2O3 nanotubes are exceptional one-dimensional transition metal oxide materials with low density, large surface area, promising electrochemical and photoelectrochemical properties, which are widely investigated in lithium-ion batteries, photoelectrochemical devices, gas sensors, and catalysis. They have drawn significant attention to the fields of energy storage and conversion, and environmental sensing and remediation due to the increase in the global energy crisis and environmental pollution. Many efforts have been made toward controlling the morphology or impurity doping to improve the intrinsic properties of α-Fe2O3 nanotubes. In this review, we introduce the synthesis methods and physicochemical properties of α-Fe2O3 nanotubes. The fabrication conditions, which are important for the physicochemical properties of materials, are also listed to describe the synthesis processes. Furthermore, the development and breakthrough of various applications in batteries, supercapacitors, photoelectrochemical devices, environmental remediation, and sensors are systematically reviewed. Finally, some of the current challenges and future perspectives for α-Fe2O3 nanotubes are discussed. We believe that this timely and critical mini-review will stimulate extensive studies and attract more attention, further improving the development of the α-Fe2O3 (hematite) nanotube structure.
α-Fe2O3纳米管是一类特殊的一维过渡金属氧化物材料,具有低密度、大表面积以及良好的电化学和光电化学性能,在锂离子电池、光电化学器件、气体传感器及催化等领域得到了广泛研究。由于全球能源危机和环境污染的加剧,它们在能量存储与转换、环境传感与修复等领域受到了广泛关注。人们为控制α-Fe2O3纳米管的形貌或进行杂质掺杂以改善其固有性能付出了诸多努力。在这篇综述中,我们介绍了α-Fe2O3纳米管的合成方法和物理化学性质。还列出了对材料物理化学性质至关重要的制备条件,以描述合成过程。此外,系统综述了α-Fe2O3纳米管在电池、超级电容器、光电化学器件、环境修复及传感器等各种应用中的发展与突破。最后,讨论了α-Fe2O3纳米管当前面临的一些挑战和未来展望。我们相信,这篇及时且关键的小型综述将激发广泛的研究并吸引更多关注,进一步推动α-Fe2O3(赤铁矿)纳米管结构的发展。