Bifunctional nanoporous Ni-Zn electrocatalysts with super-aerophobic surface for high-performance hydrazine-assisted hydrogen production.

In the present study, an effective approach is proposed to replace the oxygen evolution reaction with the substituted anodic hydrazine oxidation reaction (HzOR) to assist in hydrogen generation based on a bifunctional porous Ni-Zn electrocatalyst with nanosheet arrays. The Ni-Zn catalyst exhibits an extraordinary HzOR performance with a high current density of 970 mA cm at 0.7 V, and 93.8% of its initial activity after 5000 s, simultaneously delivering an overpotential of 68 mV at 10 mA cm for the hydrogen evolution reaction. Moreover, the electrolytic cell is constructed employing Ni-Zn catalysts as both the anode and cathode, achieving 100 mA cm at an ultralow cell voltage of 0.497 V with an outstanding stability over 10 h. The superior electrocatalytic performance can be ascribed to its porous structure with large active surface area, high electrical conductivity, and most importantly the super-aerophobic nature of the Ni-Zn surface. This work also provides a novel approach to designing and constructing porous structured non-noble metal bifunctional electrocatalysts with super-aerophobic surface to be used for energy-saving hydrogen production.