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通过调整硫铝酸钙含量来控制硫铝酸钙水泥的热释放

Managing the Heat Release of Calcium Sulfoaluminate Cement by Modifying the Ye'elimite Content.

作者信息

Kleib Joelle, Aouad Georges, Benzerzour Mahfoud, Abriak Nor Edine, Zakhour Mirvat

机构信息

IMT Nord Europe, Institut Mines-Télécom, Centre for Materials and Processes, F-59000 Lille, France.

4515-LGCgE-Laboratoire de Génie Civil et géoEnvironnement, Institut Mines-Télécom, University Lille, University Artois, Junia, F-59000 Lille, France.

出版信息

Materials (Basel). 2023 Mar 20;16(6):2470. doi: 10.3390/ma16062470.

Abstract

Nowadays, calcium sulfoaluminate cement (CSA) is garnering a large amount of attention worldwide and is being promoted as a sustainable alternative to Portland cement for specific applications. This study aimed to control the heat release of CSA cement paste by choosing the appropriate composition. For this purpose, different calcium sulfoaluminate clinkers with up to 75 wt. % of ye'elimite were synthetized. Then, a reactivity study on the synthesized clinkers was conducted while varying the amount of gypsum added. The heat of hydration was measured by isothermal calorimetry. The influence of the ye'elimite content on the heat release and on the compressive strength was investigated. According to the findings, the amount of ye'elimite in the cement has a direct relationship with the heat release. The heat release as well as the mechanical performance increase with the increase in the ye'elimite content in the CSA cement. An equation allowing the prediction of the total heat release after 24 h is provided. Such data can be of particular interest to consultants aiming at the reduction of thermal cracking in massive concrete.

摘要

如今,硫铝酸钙水泥(CSA)在全球范围内受到广泛关注,并被推广为波特兰水泥在特定应用中的可持续替代品。本研究旨在通过选择合适的成分来控制CSA水泥浆体的热释放。为此,合成了不同的硫铝酸钙熟料,其中钙矾石含量高达75 wt.%。然后,在改变石膏添加量的同时,对合成的熟料进行了反应性研究。通过等温量热法测量水化热。研究了钙矾石含量对热释放和抗压强度的影响。根据研究结果,水泥中钙矾石的含量与热释放有直接关系。CSA水泥中热释放和力学性能随着钙矾石含量的增加而增加。提供了一个可预测24小时后总热释放的方程。这些数据对于旨在减少大体积混凝土热裂缝的顾问来说可能特别有用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/263d/10052529/ac99a69fa2e0/materials-16-02470-g001.jpg

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