Kouton Aniffa, Gao Yafei, Carta Veronica
Department of Chemistry, Indiana University, 800 E Kirkwood Street, 47405, Bloomington (IN), USA.
Acta Crystallogr E Crystallogr Commun. 2020 Apr 21;76(Pt 5):673-676. doi: 10.1107/S2056989020005058. eCollection 2020 May 1.
The solid-state structure of bis-(1-mesityl-1-imidazole-κ )di-phenyl-boron tri-fluoro-methane-sulfonate, CHBN ·CFSO or (), is reported. Bis(1-mesityl-1-imidazole-κ )di-phenyl-boron ( ) is a bulky ligand that crystallizes in the ortho-rhom-bic space group . The asymmetric unit contains one cationic ligand and one tri-fluoro-methane-sulfonate anion that balances the positive charge of the ligand. The tetra-hedral geometry around the boron center is distorted as a result of the steric bulk of the phenyl groups. Weak inter-actions, such as π-π stacking are present in the crystal structure.
报道了双(1-均三甲苯基-1-咪唑-κ)二苯基硼三氟甲磺酸盐(CHBN·CFSO 或())的固态结构。双(1-均三甲苯基-1-咪唑-κ)二苯基硼()是一种体积较大的配体,结晶于正交空间群。不对称单元包含一个阳离子配体和一个平衡配体正电荷的三氟甲磺酸盐阴离子。由于苯基的空间位阻,硼中心周围的四面体几何形状发生扭曲。晶体结构中存在诸如π-π堆积等弱相互作用。