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薛定谔方程的束缚态解及其在某些双原子分子中的应用。

Bound state solutions of the Schrödinger equation and its application to some diatomic molecules.

作者信息

Onate C A, Abolarinwa A, Salawu S O, Oladejo N K

机构信息

Department of Physical Sciences, Landmark University, Omu-Aran, Nigeria.

出版信息

J Mol Model. 2020 May 20;26(6):145. doi: 10.1007/s00894-020-04359-8.

Abstract

We apply the supersymmetric quantum mechanics and shape invariance approach to obtain the solutions of the 3-dimensional Schrödinger equation in the presence of a newly proposed potential model called hyperbolic-sinus potential function for any ℓ-state. Rotational-vibrational energy eigenvalues of some diatomic molecules are numerically calculated. Special cases of interest of the hyperbolic-sinus potential function are also studied. Our results indicated that the energy eigenvalue is highly sensitive to the potential parameters.

摘要

我们应用超对称量子力学和形状不变性方法,在存在一种新提出的称为双曲正弦势函数的势模型的情况下,获得任意ℓ态下三维薛定谔方程的解。对一些双原子分子的转动 - 振动能量本征值进行了数值计算。还研究了双曲正弦势函数的一些特殊有趣情况。我们的结果表明,能量本征值对势参数高度敏感。

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