Ma Hongqiang, Sun Jianwei, Wu Chao, Yi Cheng, Li Yu
School of Mechanics and Civil Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China.
Dept. Civil and Natural Resources Engineering, University of Canterbury, Christchurch 8041, New Zealand.
Materials (Basel). 2020 May 27;13(11):2442. doi: 10.3390/ma13112442.
Just as it is regarding ordinary cement-based materials, the pore structure and microstructure of alkali-activated materials are disordered. It is essential to predict the macroscopic properties by studying the pore and microstructure fractal characteristics of materials. In this paper, the effects of slag content and alkali activator modulus on compressive strength, porosity, and microstructure of alkali-activated coal gangue-slag (AACGS) mortar were studied. Further, with the help of mercury intrusion porosimetry (MIP) data and the MATLAB programming, the pore and SEM photos fractal dimensions of AACGS mortar specimens were obtained, respectively, and the relationship between the microscopic fractal dimensions and the macroscopic strength and the structural characteristics of pores was established. The results show that the pore fractal dimension has a good linear relationship with the compressive strength and pore characteristic parameters (porosity, total pore area, and average pore diameter, etc.). With the increase of slag content, the SEM photos fractal dimension of AACGS mortar specimens increases, and the fractal dimension and compressive strength also show a significant positive linear relationship. The two fractal characterization methods can be used in the alkali-activated material system and have important guiding significance for predicting the macroscopic strength and pore characteristic parameters of the material.
与普通水泥基材料一样,碱激发材料的孔隙结构和微观结构是无序的。通过研究材料的孔隙和微观结构分形特征来预测宏观性能至关重要。本文研究了矿渣含量和碱激发剂模量对碱激发煤矸石-矿渣(AACGS)砂浆抗压强度、孔隙率和微观结构的影响。此外,借助压汞法(MIP)数据和MATLAB编程,分别获得了AACGS砂浆试件的孔隙和扫描电子显微镜(SEM)照片分形维数,并建立了微观分形维数与宏观强度及孔隙结构特征之间的关系。结果表明,孔隙分形维数与抗压强度及孔隙特征参数(孔隙率、总孔隙面积和平均孔径等)具有良好的线性关系。随着矿渣含量的增加,AACGS砂浆试件的SEM照片分形维数增大,且分形维数与抗压强度也呈现出显著的正线性关系。这两种分形表征方法可应用于碱激发材料体系,对预测材料的宏观强度和孔隙特征参数具有重要的指导意义。