用AgSCF对β-硝基苯乙烯进行几何选择性脱硝基三氟甲硫基化反应以制备（）-乙烯基三氟甲硫醚
Geometrically Selective Denitrative Trifluoromethylthiolation of β-Nitrostyrenes with AgSCF for ()-Vinyl Trifluoromethyl Thioethers.
作者信息
Zheng Changge, Huang Shuai, Liu Yang, Jiang Chao, Zhang Wei, Fang Ge, Hong Jianquan
机构信息
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, P. R. China.
School of Chemical Engineering, Xinjiang Agricultural University, Urumqi, Xinjiang Uygur Autonomous Region 830052, P. R. China.
出版信息
Org Lett. 2020 Jun 19;22(12):4868-4872. doi: 10.1021/acs.orglett.0c01714. Epub 2020 Jun 1.
An efficient copper(II)-promoted denitrative trifluoromethylthiolation under mild reaction conditions has been developed for vinyl trifluoromethyl thioethers to construct C-SCF bonds with stable AgSCF as a source of the trifluoromethylthio. This reaction system tolerates a broad range of functional groups to commendably achieve a high product yield and excellent stereoselectivity of /.
已开发出一种在温和反应条件下由铜（II）促进的脱硝基三氟甲硫基化反应，用于乙烯基三氟甲硫醚，以稳定的AgSCF作为三氟甲硫基源构建C-SCF键。该反应体系能耐受多种官能团，可出色地实现高产物收率和优异的立体选择性。
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